TABLE 4.

Calculated rate coefficients for the ^•CH₂NH₂ + O₂, ^•CH₂NH₂ +O₂ (+NH₃), and ^•CH₂NH₂ +O₂ (+H₂O) in the temperature range of 200 K–400 K at 1 bar pressure.

Temperature	•CH2NH2 + O2	Exp. value Rissanen et al. (2014)	32CH2OH + O2	•CH2NH2+O2 (+NH3)	•CH2NH2 +O2 (+H2O)
200	3.9 × 10−11	1.9 × 10−11	5.6 × 10−11	1.9 × 10−22	9.8 × 10−20
225	3.1 × 10−11	2.2 × 10−11	4.6 × 10−11	8.6 × 10−23	7.8 × 10−19
250	2.4 × 10−11	2.4 × 10−11	3.8 × 10−11	4.8 × 10−23	3.7 × 10−18
275	2.0 × 10−11	2.7 × 10−11	3.3 × 10−11	3.0 × 10−23	1.3 × 10−17
298	1.7 × 10−11	2.9 × 10−11	2.8 × 10−11	1.9 × 10−23	3.3 × 10−17
300	1.6 × 10−11	2.8 × 10−11	2.85 × 10−11	1.9 × 10−23	3.3 × 10−17
325	1.4 × 10−11	3.1 × 10−11	2.6 × 10−11	1.4 × 10−23	7.4 × 10−17
350	1.2 × 10−11	3.4 × 10−11	2.3 × 10−11	1.1 × 10−23	1.4 × 10−16
375	0.9 × 10−11	3.6 × 10−11	2.1 × 10−11	8.7 × 10−24	2.3 × 10−16
400	0.8 × 10−11	3.8 × 10−11	1.9 × 10−11	7.4 × 10−24	4.0 × 10−16
k = ATn	A = 0.02		A = 1.0 × 10−09	A = 4.8 × 10−31	A = 3.5×105
	n = −3.4		n = −0.75	n = 2.0	n = −6.0
exp (−B/T)	B = 323		B = −222	B = −1858	B = 4958