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. Author manuscript; available in PMC: 2023 Oct 5.
Published in final edited form as: Polym Chem. 2022 Aug 8;13(33):4798–4808. doi: 10.1039/D2PY00603K

Fig. 7.

Fig. 7

PTO RAFT polymerizations of n-butyl acrylate run with 6 mM AIBN (A), 6 mM AIBN and 300 μM V-70 (B), and 6 mM V-70 (C). PTO RAFT polymerizations conducted in continuous flow with either 6 mM AIBN (Condition A) or 300 μM V-70 and 6 mM AIBN (Condition B) (D). All polymer molecular weights were calculated using multi-angle light scattering. Conditions: [AIBN] = 6 mM, [V-70] = 300 uM (Condition A) or solely [AIBN] = 6 mM (Condition B). aConversion calculated from 1H NMR relative to an internal standard. b2-(Butylthiocarbonothioylthio)propanoic acid (BTTCP) used as the CTA in a monomer : CTA molar ratio of 200 : 1 in dioxane at 80 °C and ran for 30 minutes. cCyanomethyl dodecyl trithiocarbonate (CMDT) used as the CTA in a monomer : CTA molar ratio of 100 : 1 in DMF at 80 °C and ran for 15 minutes. dDibenzyl trithiocarbonate (DBTTC) used as the CTA in a monomer : CTA molar ratio of 300 : 1 in dichlorobenzene with 6 mM ABCN used in place of AIBN at 100 °C and ran for 2 hours. e2-Cyano-2-propyl benzodithioate (CPDB) used as the CTA in a monomer : CTA molar ratio of 200 : 1 in toluene at 100 °C and ran for 20 minutes.