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. 2023 Sep 22;145(39):21623–21629. doi: 10.1021/jacs.3c07974

Table 2. Decarboxylative Synthesis of Sulfinamides 1a.

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a

Reaction conditions: (i) carboxylic acid (0.2 mmol), R-NSO (0.3 mmol), PC2 (10 mol %), 395–405 nm LEDs, CH2Cl2 (4 mL), rt, and 18 h. Isolated yields.

b

Carboxylic acid (0.3 mmol), Tr-NSO (0.2 mmol).

c

CH2Cl2 (1 mL).

d

Using PC1.

e

PC2 (20 mol %).

f

Using t-Oct-NSO in place of Tr-NSO.

g

Using (i-Pr)3Si-NSO (0.2 mmol) in place of Tr-NSO, carboxylic acid (0.3 mmol).

h

Using t-BuO-NSO (0.2 mmol) in place of Tr-NSO, carboxylic acid (0.3 mmol).