Cu1—O2 | 1.960 (4) | C2—H2A | 0.9900 |
Cu1—O4i | 2.023 (4) | C2—H2B | 0.9900 |
Cu1—O6 | 1.963 (4) | C2—C3 | 1.526 (8) |
Cu1—O8i | 1.961 (4) | C3—H3A | 0.9900 |
Cu1—N4ii | 2.197 (5) | C3—H3B | 0.9900 |
Cu2—O1 | 1.979 (4) | C3—C4 | 1.515 (8) |
Cu2—O3i | 1.990 (4) | C5—C6 | 1.528 (8) |
Cu2—O5 | 1.980 (4) | C6—H6A | 0.9900 |
Cu2—O7i | 1.973 (4) | C6—H6B | 0.9900 |
Cu2—N1 | 2.167 (5) | C6—C7 | 1.522 (8) |
O1—C1 | 1.265 (7) | C7—H7A | 0.9900 |
O2—C1 | 1.264 (7) | C7—H7B | 0.9900 |
O3—C4 | 1.248 (7) | C7—C8 | 1.519 (8) |
O4—C4 | 1.271 (7) | C9—H9 | 0.9500 |
O5—C5 | 1.249 (7) | C9—C10 | 1.386 (9) |
O6—C5 | 1.263 (7) | C10—H10 | 0.9500 |
O7—C8 | 1.254 (7) | C10—C11 | 1.361 (9) |
O8—C8 | 1.256 (7) | C11—H11 | 0.9500 |
O9—C14 | 1.218 (7) | C11—C12 | 1.392 (8) |
N1—C9 | 1.333 (8) | C12—C13 | 1.389 (8) |
N1—C13 | 1.340 (7) | C13—H13 | 0.9500 |
N2—H2 | 0.8800 | C15—H15 | 0.9500 |
N2—C12 | 1.401 (8) | C15—C16 | 1.387 (9) |
N2—C14 | 1.371 (8) | C16—H16 | 0.9500 |
N3—H3 | 0.8800 | C16—C17 | 1.383 (9) |
N3—C14 | 1.376 (8) | C17—H17 | 0.9500 |
N3—C18 | 1.400 (8) | C17—C18 | 1.383 (8) |
N4—C15 | 1.335 (8) | C18—C19 | 1.385 (8) |
N4—C19 | 1.327 (8) | C19—H19 | 0.9500 |
C1—C2 | 1.504 (8) | ||
O2—Cu1—O4i | 90.48 (18) | O3—C4—O4 | 125.4 (5) |
O2—Cu1—O6 | 87.41 (18) | O3—C4—C3 | 119.0 (5) |
O2—Cu1—O8i | 166.45 (17) | O4—C4—C3 | 115.5 (5) |
O2—Cu1—N4ii | 91.11 (18) | O5—C5—O6 | 126.1 (6) |
O4i—Cu1—N4ii | 89.25 (17) | O5—C5—C6 | 117.9 (6) |
O6—Cu1—O4i | 169.11 (17) | O6—C5—C6 | 115.9 (5) |
O6—Cu1—N4ii | 101.47 (18) | C5—C6—H6A | 108.5 |
O8i—Cu1—O4i | 88.52 (17) | C5—C6—H6B | 108.5 |
O8i—Cu1—O6 | 91.03 (18) | H6A—C6—H6B | 107.5 |
O8i—Cu1—N4ii | 102.38 (18) | C7—C6—C5 | 115.0 (5) |
O1—Cu2—O3i | 89.16 (18) | C7—C6—H6A | 108.5 |
O1—Cu2—O5 | 90.34 (18) | C7—C6—H6B | 108.5 |
O1—Cu2—N1 | 95.10 (17) | C6—C7—H7A | 108.6 |
O3i—Cu2—N1 | 99.11 (18) | C6—C7—H7B | 108.6 |
O5—Cu2—O3i | 166.52 (17) | H7A—C7—H7B | 107.6 |
O5—Cu2—N1 | 94.36 (18) | C8—C7—C6 | 114.6 (5) |
O7i—Cu2—O1 | 168.62 (18) | C8—C7—H7A | 108.6 |
O7i—Cu2—O3i | 88.50 (18) | C8—C7—H7B | 108.6 |
O7i—Cu2—O5 | 89.35 (19) | O7—C8—O8 | 126.2 (6) |
O7i—Cu2—N1 | 96.27 (18) | O7—C8—C7 | 117.2 (6) |
C1—O1—Cu2 | 119.2 (4) | O8—C8—C7 | 116.6 (5) |
C1—O2—Cu1 | 127.8 (4) | N1—C9—H9 | 119.2 |
C4—O3—Cu2iii | 123.8 (4) | N1—C9—C10 | 121.6 (6) |
C4—O4—Cu1iii | 122.6 (4) | C10—C9—H9 | 119.2 |
C5—O5—Cu2 | 124.8 (4) | C9—C10—H10 | 120.2 |
C5—O6—Cu1 | 121.1 (4) | C11—C10—C9 | 119.7 (6) |
C8—O7—Cu2iii | 125.0 (4) | C11—C10—H10 | 120.2 |
C8—O8—Cu1iii | 120.7 (4) | C10—C11—H11 | 120.3 |
C9—N1—Cu2 | 120.0 (4) | C10—C11—C12 | 119.5 (6) |
C9—N1—C13 | 119.1 (5) | C12—C11—H11 | 120.3 |
C13—N1—Cu2 | 120.7 (4) | C11—C12—N2 | 118.4 (6) |
C12—N2—H2 | 116.9 | C13—C12—N2 | 123.7 (6) |
C14—N2—H2 | 116.9 | C13—C12—C11 | 117.9 (6) |
C14—N2—C12 | 126.1 (5) | N1—C13—C12 | 122.3 (6) |
C14—N3—H3 | 116.7 | N1—C13—H13 | 118.8 |
C14—N3—C18 | 126.5 (5) | C12—C13—H13 | 118.8 |
C18—N3—H3 | 116.7 | O9—C14—N2 | 123.6 (6) |
C15—N4—Cu1iv | 129.1 (4) | O9—C14—N3 | 122.9 (6) |
C19—N4—Cu1iv | 111.2 (4) | N2—C14—N3 | 113.4 (6) |
C19—N4—C15 | 118.6 (6) | N4—C15—H15 | 119.2 |
O1—C1—C2 | 118.4 (5) | N4—C15—C16 | 121.5 (6) |
O2—C1—O1 | 124.7 (6) | C16—C15—H15 | 119.2 |
O2—C1—C2 | 116.9 (5) | C15—C16—H16 | 120.3 |
C1—C2—H2A | 108.9 | C17—C16—C15 | 119.4 (6) |
C1—C2—H2B | 108.9 | C17—C16—H16 | 120.3 |
C1—C2—C3 | 113.5 (5) | C16—C17—H17 | 120.5 |
H2A—C2—H2B | 107.7 | C18—C17—C16 | 119.0 (6) |
C3—C2—H2A | 108.9 | C18—C17—H17 | 120.5 |
C3—C2—H2B | 108.9 | C17—C18—N3 | 120.1 (6) |
C2—C3—H3A | 108.6 | C17—C18—C19 | 117.7 (6) |
C2—C3—H3B | 108.6 | C19—C18—N3 | 122.1 (6) |
H3A—C3—H3B | 107.5 | N4—C19—C18 | 123.7 (6) |
C4—C3—C2 | 114.8 (5) | N4—C19—H19 | 118.2 |
C4—C3—H3A | 108.6 | C18—C19—H19 | 118.2 |
C4—C3—H3B | 108.6 | ||
Cu1—O2—C1—O1 | 4.2 (9) | N4—C15—C16—C17 | −1.5 (9) |
Cu1—O2—C1—C2 | −175.2 (4) | C1—C2—C3—C4 | −78.3 (7) |
Cu1iii—O4—C4—O3 | 5.2 (8) | C2—C3—C4—O3 | −22.2 (8) |
Cu1iii—O4—C4—C3 | −177.9 (4) | C2—C3—C4—O4 | 160.7 (5) |
Cu1—O6—C5—O5 | 2.4 (9) | C5—C6—C7—C8 | 75.8 (7) |
Cu1—O6—C5—C6 | 179.4 (4) | C6—C7—C8—O7 | 32.4 (8) |
Cu1iii—O8—C8—O7 | 0.4 (9) | C6—C7—C8—O8 | −149.6 (5) |
Cu1iii—O8—C8—C7 | −177.5 (4) | C9—N1—C13—C12 | 0.7 (9) |
Cu1iv—N4—C15—C16 | 167.8 (4) | C9—C10—C11—C12 | 0.3 (9) |
Cu1iv—N4—C19—C18 | −169.4 (5) | C10—C11—C12—N2 | 179.0 (6) |
Cu2—O1—C1—O2 | 4.5 (8) | C10—C11—C12—C13 | 0.0 (9) |
Cu2—O1—C1—C2 | −176.2 (4) | C11—C12—C13—N1 | −0.5 (9) |
Cu2iii—O3—C4—O4 | 0.4 (8) | C12—N2—C14—O9 | −6.2 (9) |
Cu2iii—O3—C4—C3 | −176.4 (4) | C12—N2—C14—N3 | 175.0 (5) |
Cu2—O5—C5—O6 | 2.4 (9) | C13—N1—C9—C10 | −0.3 (9) |
Cu2—O5—C5—C6 | −174.6 (4) | C14—N2—C12—C11 | 174.2 (5) |
Cu2iii—O7—C8—O8 | 5.8 (9) | C14—N2—C12—C13 | −6.8 (9) |
Cu2iii—O7—C8—C7 | −176.4 (4) | C14—N3—C18—C17 | −166.6 (6) |
Cu2—N1—C9—C10 | 174.5 (5) | C14—N3—C18—C19 | 16.7 (9) |
Cu2—N1—C13—C12 | −174.1 (4) | C15—N4—C19—C18 | −0.2 (9) |
O1—C1—C2—C3 | 157.7 (5) | C15—C16—C17—C18 | 1.6 (9) |
O2—C1—C2—C3 | −22.9 (8) | C16—C17—C18—N3 | −177.7 (5) |
O5—C5—C6—C7 | −150.1 (6) | C16—C17—C18—C19 | −0.9 (9) |
O6—C5—C6—C7 | 32.6 (8) | C17—C18—C19—N4 | 0.3 (9) |
N1—C9—C10—C11 | −0.2 (10) | C18—N3—C14—O9 | −1.0 (10) |
N2—C12—C13—N1 | −179.5 (5) | C18—N3—C14—N2 | 177.8 (5) |
N3—C18—C19—N4 | 177.0 (5) | C19—N4—C15—C16 | 0.8 (9) |