Table 2. Photoelectrochemical Performances of Literature Benchmark CuWO4 Photoanodes Prepared with Different Synthetic Approaches.
| Jg | stability |
|||||
|---|---|---|---|---|---|---|
| synthetic method | electrolyte | thickness/nm | / mA cm–2 | Time / min | Jfinh / mA cm-2–2jfinh | ref |
| spin-coating | 0.1 M KPi (pH 7) | 580 | 0.37 | 120 | 0.37 | this work |
| one step-hya | 0.2 M KPi (pH 7)e | ∼1500 | 0.38 | 50 | 0.3 | (43) |
| ST – hyb | 0.1 M KPi (pH 7) | ≥1000 | ∼0.3 | 60 | ∼5%i | (44) |
| ST – hy | 0.1 M KPi (pH 7) | ≥1000 | 0.34 | 240 | ∼35%i | (45) |
| ST – hy | 1 M KBi (pH 9)f | ≥1000 | 0.4 | 60 | 0.39 | (29) |
| ST – hy | 0.1 M KPi (pH 7) | 2000 | 0.42 | n/a | n/a | (46) |
| ST – hy | 0.1 M KPi (pH 7) | ≥1000 | 0.35 | 240 | 0.26 | (47) |
| spin-coating | KPi (pH 7) | 500 | 0.47 | 600 | 0.4 | (48) |
| e-depositionc | 0.1 M KPi (pH 7) | 2–3000 | 0.18 | 600 | ∼50%i | (25) |
| ALDd | 1 M KBi (pH 9.0) | 80 | ∼0.15 | n/a | n/a | (41) |
| ST - hy | 0.1 M Kpi (pH 7) | ≥1000 | 0.35 | 60 | ∼17%i | (22) |
| spin coating | 0.1 M Na2SO4 (pH 6.8) | 800 | 0.27 | 2.5 | 0.21 | (49) |
| spray pyrolysis | 0.1 M KPi (pH 7) | 1.5–2000 | 0.19 | n/a | n/a | (50) |
| spin coating | KPi/NaCl 0.1/0.14 M | 250 | 0.38 | n/a | n/a | (51) |
| ST – hy | 0.1 M KPi (pH 7) | ≥1000 | 0.38 | 240 | 0.39 | (52) |
one-step hydrothermal.
sacrificial template–hydrothermal.
electrodeposition.
atomic layer deposition.
potassium phosphate buffer.
potassium borate buffer.
current density at 1.23 VSHE,
current density at 1.23 VSHE at the end of the stability test,
current density percent drop at the end of the stability test (in this case the stability is at a voltage ≥1.23 VSHE).