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. 2023 Sep 22;14(39):10727–10735. doi: 10.1039/d3sc04375d

Overview of the photophysical properties in toluene at 295 K. ΦF: fluorescence quantum yield; τS1: excited singlet state deactivation time constant of PDI; ΦT: triplet yield from fsTA; ΦΔ: singlet oxygen quantum yield.

Compound Φ F τ S1/ps Φ T Φ Δ
PDI-ph-trityl 0.002 2.5 0.10 0.10
PDI-biph-trityl 0.04 8.7 0.12 0.10
PDI-biph-eTEMPO 0.81 5.2 × 103 n.a. 0.04