Overview of the photophysical properties in toluene at 295 K. ΦF: fluorescence quantum yield; τS1: excited singlet state deactivation time constant of PDI; ΦT: triplet yield from fsTA; ΦΔ: singlet oxygen quantum yield.
Compound | Φ F | τ S1/ps | Φ T | Φ Δ |
---|---|---|---|---|
PDI-ph-trityl | 0.002 | 2.5 | 0.10 | 0.10 |
PDI-biph-trityl | 0.04 | 8.7 | 0.12 | 0.10 |
PDI-biph-eTEMPO | 0.81 | 5.2 × 103 | n.a. | 0.04 |