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. 2023 Oct 5;24(19):14933. doi: 10.3390/ijms241914933
Notation
CB,exp Experimental purity of L-menthol in the final product, dimensionless
CB,the Calculated purity of L-menthol in the final product, dimensionless
L0  Mass of the initial liquid feed, g
Ln  Mass of the liquid out of stage n, g
Pn Pressure in stage n, Pa
Pjsat Saturated vapor pressure of component-j, Pa
Ptri,j Triple-point pressure of component-j, K
R Ideal gas constant, 8.314 J/molK
Sn Mass of the solid solution enriched with L-menthol formed in stage n, g
Stot,n Total amount of the solid solution enriched with L-menthol formed from stage 1 to stage n, g
Tn Temperature in stage n, K
Tb,j Boiling temperature of component-j, K
Tm,j Melting temperature of component-j, K
t Time, s
Vn Mass of the vapor formed in stage n, g
Vtot,n Total amount of vapor formed and removed from stage 1 to stage n, g
Wf,exp Measured weight of the final product at the end of TPC, g
Wf,the Calculated weight of the final product at the end of TPC, g
(Xj)0 Initial mole fraction of component-j in the liquid feed, dimensionless
(Xj)n Mole fraction of component-j in the remaining liquid in stage n, dimensionless
(Yj)n Mole fraction of component-j in the vapor phase formed in stage n, dimensionless
(Zj)n Mole fraction of component-j in the solid solution formed in stage n, dimensionless
Z¯B,the Average mole fraction of component-j in the solid solution at the end of T, dimensionless
Z¯B,exp Experimental purity of L-menthol for the final product at the end of the sweating experiment, dimensionless
Hm,j  Heat of melting for component-j (>0), J/mol
HV,j  Heat of vaporization for component-j (>0), J/mol
Lexp Amount of liquid removed at the end of the sweating experiment, g
Greek Letters
γj Activity coefficient of component-j in liquid, dimensionless
Subscript
0 In the initial feed
f At the end of TPC
n In stage n
N In the last stage