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. 2023 Oct 13;13(43):29904–29922. doi: 10.1039/d3ra04628a

Works on coatings development for biomass boiler.

Deposition method Material Key finding Ref.
HVOF Inconel 625 A lower amount of Cr and Ni and a high amount of Fe may decrease corrosion resistance 107
Inconel 718
Electric arc spraying Fe–Cr–Mo amorphous coating + sodium silicate sealant Cl acted as a catalyst for accelerating corrosion, and Fe and Cr were mainly chlorinated 108
Air plasma spraying (APS) Ni–Al (Al = 5 wt%, Ni = balance) + preoxidation at 700 °C for 6 h The porosity produces poor corrosion resistance, and pre-oxidation can hinder the ingression of corrosive species 109
HVOF Stellite-6 Adequate protection by Cr2O3 outer layer and the sub-layer rich in Co (CoCr2O4 and CoO) resulted from the Stellite-6 coating. While NiAl coating severely damaged due to a chlorine attack 110
NiAl
Electroplating + pack aluminizing Ni Nickel aluminide coating was corroded and formed AlCl3 111
Ni2Al3
HVOF Ni5Al Cr oxides were blocking inter-splat corrosion attack, thus mitigating internal corrosion 112
Fe50Cr
Ni20Cr
HVAF Ni21Cr9Mo SiO2 induces the rapid formation of dense and highly attached Cr2O3 that hinders chloride diffusion 113
SiO2-containing Ni21Cr9Mo
HVAF Ni21Cr7Al1Y Chloride reacted with Cr and Al to form CrCl3 and AlCl3 at the splat boundaries, while Mo can support the formation of a protective Cr oxide scale 114
SiO2-containing Ni21Cr9Mo
Electroplating + pack aluminizing Ni Cl species was diffuse and propagated the corrosion reaction 115
Ni2Al3
HVOF NiAl Inhibiting the diffusion of Cl2 and O2 is crucial because Cl2 acts as a catalyst, inducing the formation of NiCl2, AlCl3, and subsequent oxidation at the interface 116
HVAF NiCr (in wt%; 78.6 Ni–21.3 Cr–0.1 O) Cl may diffuse and form metal chlorides through defects and splat boundaries. Moreover, Al2O3 was found to impede the Cl diffusion 117
NiAl (in wt%; 94.1 Ni–5.7 Al–0.2 O)
HVAF Ni5Al Al-rich oxide was observed to have better protection against KCl. Cr-rich oxide was prone to degradation due to chromate formation 118
Ni21Cr
Ni21Cr7Al1Y
Ni21Cr9Mo