Table 4.
Sources of uncertainty in the determination.
| Sources of uncertainty | Mg | Zn | Cu | |||
|---|---|---|---|---|---|---|
| GBW09152 | GBW09152 | GBW09152 | ||||
| Value (xi) | u c (xi) | Value (xi) | u c (xi) | Value (xi) | u c (xi) | |
| Type A uncertainties | ||||||
| RY | 0.014 | 0.000 | 0.034 | 0.000 | 0.004 | 0.000 |
| Rz | 6.667 | 0.021 | 6.208 | 0.014 | 2.107 | 0.003 |
| RBc | 0.920 | 0.002 | 1.041 | 0.003 | 1.080 | 0.004 |
| RB | 0.885 | 0.003 | 1.004 | 0.003 | 1.049 | 0.002 |
| CB (mg·kg−1) | 0.5 | 0.3 | 0.09 | 0.05 | 0.010 | 0.005 |
| Type B uncertainties | ||||||
| Cz (mg·kg−1) | 19.398 | 0.003 | 1.290 | 0.002 | 1.008 | 0.002 |
| mzc (mg) | 3.0 × 102 | 0.040 | 2.6 × 102 | 0.040 | 5.4 × 102 | 0.040 |
| mYc (mg) | 5.5 × 102 | 0.040 | 2.0 × 102 | 0.040 | 4.0 × 102 | 0.040 |
| mY (mg) | 3.4 × 102 | 0.040 | 200 × 102 | 0.040 | 4.0 × 102 | 0.040 |
| mx (mg) | 2.0 × 102 | 0.040 | 300 × 102 | 0.040 | 4.8 × 102 | 0.040 |
| Combined types A and B | — | 0.25 | — | 0.045 | — | 0.011 |
| Degrees of freedom (Veff) | 8 | 8 | 8 | |||
| Coverage factor (k) | — | 2 | — | 2 | — | 2 |
| Measured value (mg·kg−1) | 20.57 | — | 1.147 | — | 1.072 | — |
| Expanded uncertainty (U(), k = 2) (mg·kg−1) | — | 0.2 | — | 0.04 | — | 0.08 |