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. 2023 Oct 9;2023:6612672. doi: 10.1155/2023/6612672

Table 4.

Sources of uncertainty in the determination.

Sources of uncertainty Mg Zn Cu
GBW09152 GBW09152 GBW09152
Value (xi) u c (xi) Value (xi) u c (xi) Value (xi) u c (xi)
Type A uncertainties
RY 0.014 0.000 0.034 0.000 0.004 0.000
Rz 6.667 0.021 6.208 0.014 2.107 0.003
RBc 0.920 0.002 1.041 0.003 1.080 0.004
RB 0.885 0.003 1.004 0.003 1.049 0.002
CB (mg·kg−1) 0.5 0.3 0.09 0.05 0.010 0.005
Type B uncertainties
Cz (mg·kg−1) 19.398 0.003 1.290 0.002 1.008 0.002
mzc (mg) 3.0 × 102 0.040 2.6 × 102 0.040 5.4 × 102 0.040
mYc (mg) 5.5 × 102 0.040 2.0 × 102 0.040 4.0 × 102 0.040
mY (mg) 3.4 × 102 0.040 200 × 102 0.040 4.0 × 102 0.040
mx (mg) 2.0 × 102 0.040 300 × 102 0.040 4.8 × 102 0.040
Combined types A and B 0.25 0.045 0.011
Degrees of freedom (Veff) 8 8 8
Coverage factor (k) 2 2 2
Measured value (mg·kg−1) 20.57 1.147 1.072
Expanded uncertainty (U(x¯), k = 2) (mg·kg−1) 0.2 0.04 0.08