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Metabolic inhibitors disrupt glycan biosynthesis. (A) Schematic of benzyl glycosides acting as metabolic inhibitors to divert glycan biosynthesis onto decoy substrates, ultimately leading to truncated glycans on bacteria. (B) Precedented O-glycoside inhibitors from previous work. (C) Novel S-glycoside analogues of bacterial sugar scaffolds used as putative metabolic inhibitors in this study.
