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. 2023 Oct 3;8(41):38658–38667. doi: 10.1021/acsomega.3c05932

Table 4. Molecular Properties of PGBS and PGBAT Copolymers Synthesized Using Mechanical Stirring with an nGA Feed Value of 90% on a 60 g Scalea.

    feed polymer          
sample time/h nGA/mol % nGA/mol % B:A + T Mn/g mol–1 Mw/g mol–1 Đ yield/%
PGBS90 4 90 90 1:0.97b 54,800 97,000 1.77 97
PGBAT88 8 90 88 1:1.04 19,500 49,400 2.53 95
a

Polycondensation temperature was 210 °C. Both copolymers were synthesized using a B:A + T = 1.05:1.

b

B:S value.