TABLE 1.
Experimentally determined diffusion parameters for water monomers on Ir(111), GrIr(111), and GrNi(111).
| Diffusion parameters | |||||
|---|---|---|---|---|---|
| α at ΔK = 1 Å−1 (ps−1) | τ (ps) | D (m2/s) | E a (meV) | α 0 (ps−1) | |
| Ir(111) | 1,200 ± 300 | (1.5 ± 0.4) × 10−11 | 90 ± 40 | - | |
| GrIr(111) | - | - | - | ||
| GrNi(111) | 65 ± 3 | (4.1 ± 0.2) × 10−10 | 60 ± 4 | 5 ± 1 | |
The columns provide the following: the dephasing rate α, resident time τ, diffusion coefficient D, activation energy E a , and the Arrhenius prefactor α 0. Values for GrIr(111) are provided as approximate upper limits. Standard deviation is found through error propagation. Values for GrNi(111) are taken from the study by Tamtögl et al. (2021).