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. 2023 Oct 20;13(44):30855–30868. doi: 10.1039/d3ra03797e

Substrate scope for oxidation reaction under ultrasonic irradiationa.

graphic file with name d3ra03797e-u2.jpg
Entry Alcohol Product Time (h) Yieldb (%) Selectivity (%)
1 graphic file with name d3ra03797e-u3.jpg graphic file with name d3ra03797e-u4.jpg 2.0 90 100
2 graphic file with name d3ra03797e-u5.jpg graphic file with name d3ra03797e-u6.jpg 2.0 82 100
3 graphic file with name d3ra03797e-u7.jpg graphic file with name d3ra03797e-u8.jpg 2.0 86 100
4 graphic file with name d3ra03797e-u9.jpg graphic file with name d3ra03797e-u10.jpg 2.5 80 100
5 graphic file with name d3ra03797e-u11.jpg graphic file with name d3ra03797e-u12.jpg 2 85 100
6 graphic file with name d3ra03797e-u13.jpg graphic file with name d3ra03797e-u14.jpg 2.5 82 100
7 graphic file with name d3ra03797e-u15.jpg graphic file with name d3ra03797e-u16.jpg 2.0 84 100
8 graphic file with name d3ra03797e-u17.jpg graphic file with name d3ra03797e-u18.jpg 2.0 88 100
9 graphic file with name d3ra03797e-u19.jpg graphic file with name d3ra03797e-u20.jpg 1.5 94 100
10 graphic file with name d3ra03797e-u21.jpg graphic file with name d3ra03797e-u22.jpg 1.5 93 100
11 graphic file with name d3ra03797e-u23.jpg graphic file with name d3ra03797e-u24.jpg 4.0 15
12 graphic file with name d3ra03797e-u25.jpg graphic file with name d3ra03797e-u26.jpg 4.0 20
13 graphic file with name d3ra03797e-u27.jpg graphic file with name d3ra03797e-u28.jpg 5.0 Trace
14 graphic file with name d3ra03797e-u29.jpg graphic file with name d3ra03797e-u30.jpg 7.0 Trace
15 CH3(CH2)6CH2OH
a

Reaction condition: benzyl alcohol (1.0 mmol), TBHP (1.5 mmol), catalyst (sample MnF-1; 15.0 mg).

b

Isolated yield.