Substrate scope for oxidation reaction under ultrasonic irradiationa.
| |||||
|---|---|---|---|---|---|
| Entry | Alcohol | Product | Time (h) | Yieldb (%) | Selectivity (%) |
| 1 |
|
|
2.0 | 90 | 100 |
| 2 |
|
|
2.0 | 82 | 100 |
| 3 |
|
|
2.0 | 86 | 100 |
| 4 |
|
|
2.5 | 80 | 100 |
| 5 |
|
|
2 | 85 | 100 |
| 6 |
|
|
2.5 | 82 | 100 |
| 7 |
|
|
2.0 | 84 | 100 |
| 8 |
|
|
2.0 | 88 | 100 |
| 9 |
|
|
1.5 | 94 | 100 |
| 10 |
|
|
1.5 | 93 | 100 |
| 11 |
|
|
4.0 | 15 | — |
| 12 |
|
|
4.0 | 20 | — |
| 13 |
|
|
5.0 | Trace | — |
| 14 |
|
|
7.0 | Trace | — |
| 15 | CH3(CH2)6CH2OH | — | — | — | — |
Reaction condition: benzyl alcohol (1.0 mmol), TBHP (1.5 mmol), catalyst (sample MnF-1; 15.0 mg).
Isolated yield.