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. Author manuscript; available in PMC: 2024 Oct 11.
Published in final edited form as: J Am Chem Soc. 2023 Oct 3;145(40):21738–21744. doi: 10.1021/jacs.3c08428

Table 2.

Amine Scopea

graphic file with name nihms-1937179-t0004.jpg
a

Yields are the average of two experiments and are for isolated material on 0.5 mmol scale unless otherwise noted.

b

[Ir-A]OTf photocatalyst, PhCF3 solvent.

c

[Ir-B]OTf photocatalyst, dioxane solvent.

d

[Ir-A]OTf photocatalyst, dioxane solvent.

e

[Ir-B]OTf photocatalyst, PhCF3 solvent.

f

2.5 equiv. alkene.

g

Yield was determined via 1H NMR spectroscopic analysis of the crude reaction mixture relative to an internal standard.

h

Reaction was conducted on 0.2 mmol scale.

i

Methylene cyclopentane was employed as the alkene partner.