Table 1. Chromatographic, Spectrophotometric, and Mass Spectrometric Data of the Analyzed Products of Amaranthin, Argentianin, and Celosianin Oxidation by ABTS Radicals.

no.	abbrev.	compound	Rt [min]		λmax [nm]			m/z [M + H]+			m/z from MS/MS of [M + H]+
Amaranthin Oxidation
1	2,3-OH-2dAm	2,3-dihydroxy-2-decarboxy-xanamaranthin	4.0		527		715			539; 377; 359
1′	2,3-OH-2dIAm	2,3-dihydroxy-2-decarboxy- -xanisoamaranthin	4.5		527		715			539; 377; 359
2	Am	amaranthin	4.7		534		727			551; 389; 343; 297; 255
2′	IAm	isoamaranthin	5.2		534		727			551; 389; 343; 297; 255
3	2-dXAm	2-decarboxy-xanamaranthin	7.4		445		681			505; 459; 343
4	2,17-dXAm	2,17-bidecarboxy-xanamaranthin	7.8		427		637			461; 417
5	17-dNAm	17-decarboxy-neoamaranthin	7.9		480		681			505; 459; 343
6	2,17-dXNAm	2,17-bidecarboxy-xanneoamaranthin	9.6		412		635			459
7	2,17-dNAm	2,17-bidecarboxy-neoamaranthin	10.2		452		637			461; 417
8	2-dXNAm	2-decarboxy-xanneoamaranthin	12.3		422		679			503; 459; 341; 297; 253
Argentianin Oxidation
9	2,3-OH-2dArg	2,3-dihydroxy-2-decarboxy-xanargentianin		7.5		531			861			539; 377; 359
9′	2,3-OH-2dIArg	2,3-dihydroxy-2-decarboxy- -xanisoargentianin		7.5		531			861			539; 377; 359
10	Arg	argentianin		8.3		540			873			551; 389; 343; 297; 255
10′	IArg	isoargentianin		8.7		540			873			551; 389; 343; 297; 255
11	17-dNArg	17-decarboxy-neoargentianin		11.2		450			827			681; 505; 343;297
12	2,17-dXArg	2,17-bidecarboxy-xanargentianin		11.8		465			783			637; 461; 417; 299; 253
13	2,17-dXNArg	2,17-bidecarboxy-xanneoargentianin		13.3		426			781			459; 297; 251
14	2,17-dNArg	2,17-bidecarboxy-neoargentianin		13.4		426			783			637; 461; 417; 299; 253
15	2-dXNArg	2-decarboxy-xanneoargentianin		15.9		435			825			679; 503; 459; 341; 295; 251
Celosianin Oxidation
16	2,3-OH-2dCel	2,3-dihydroxy-2-decarboxy-xancelosianin		8.0	532				891			873; 829; 539; 521; 377; 359
16′	2,3-OH-2dICel	2,3-dihydroxy-2-decarboxy- -xanisocelosianin		8.1	532				891			873; 829; 539; 521; 377; 359
17	Cel	celosianin		8.8	541				903			551; 389; 343; 297; 253
17′	ICel	isocelosianin		9.0	541				903			551; 389; 343; 297; 253
18	17-dNCel	17-decarboxy-neocelosianin		11.4	452				857			681; 505; 459; 343; 297; 253
19	2,17-dXCel	2,17-bidecarboxy-xancelosianin		11.6	460				813			461; 417; 299; 253
20	2,17-dXNCel	2,17-bidecarboxy-xanneocelosianin		13.1	415				811			459; 297; 251
21	2,17-dNCel	2,17-bidecarboxy-neocelosianin		13.5	466				813			461; 417; 299; 253
22	2-dXNCel	2-decarboxy-xanneocelosianin		15.6	432				855			503; 459; 341; 295