Table 4.
Method of selenium modification for polyphenols.
| Selenization System | Principal Operating Parameter | Selenium Content/(mg/g) | Combination | Reference | 
|---|---|---|---|---|
| Dihydromyricetin-Na2SeO3 | 2 g dihydromyricetin, 0.54 g Na2SeO3 55% ethanol 60 mL 1 mol/L HCl to adjust pH to 3–4 Reaction at 55 °C for 20 min Vacuum drying for 48 h | 6.54 | C-Se | [66] | 
| Tea polyphenols-selenium | 0.2 g tea polyphenols were dissolved in H2O and added to the Se4+ solution. pH = 4–5 60 °C for 20 min | \ | Se4+ substituted C-H on the benzene ring | [67] | 
| Quercetin-SeO₂ | Quercetin 0.75 g (2.5 mmol) 0.14 g (1.25 mmol) of SeO₂ dissolved in 10 mL of absolute ethanol. Keep the pH at 2–3 The reaction was carried out at 60 °C for 10 h under N2 protection | 43.53 | Se-O | [68] |