Table A1.
The binary matrix of phenolic compounds identified by UHPLC-MS (1—present, 0—absent).
| Compound | Root | Stem | Leaf | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| № | Rt, min | m/z, [M-H]- | Formula | Name | Control | Cu 100 µM | Cu 300 µM | Control | Cu 100 µM | Cu 300 µM | Control | Cu 100 µM | Cu 300 µM |
| 1 | 2.09 | 289.07 | C15H14O6 | Catechin | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| 2 | 10.05 | 301.03 | C15H10O7 | Quercetin | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
| 3 | 5.92 | 609.15 | C27H30O16 | Rutin | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 4 | 8.3 | 227.07 | C14H12O3 | Resveratrol | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 1 | 1 |
| 5 | 0.64 | 169.01 | C7H6O5 | Gallic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 6 | 5.6 | 137.02 | C7H6O3 | Salicylic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 7 | 9.23 | 147.04 | C9H8O2 | Cinnamic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 8 | 3.96 | 163.04 | C9H8O3 | p-Coumaric acid | 1 | 1 | 1 | 0 | 0 | 0 | 0 | 1 | 1 |
| 9 | 4.61 | 193.05 | C10H10O4 | Ferulic acid | 0 | 1 | 1 | 0 | 1 | 1 | 0 | 1 | 1 |
| 10 | 2.34 | 167.03 | C8H8O4 | Vanillic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 11 | 2.74 | 197.05 | C9H10O5 | Syringic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 12 | 4.91 | 121.01 | C7H6O2 | Benzoic acid | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| 13 | 0.62 | 125.02 | C6H6O3 | Phloroglucinol | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |