. 2023 Aug 17;25(21):8558–8569. doi: 10.1039/d3gc01911j

M _n, Đ, and the physical characterisation of the thermally synthesised polymers (T_g and WCA). Conversions of all the obtained polymers were >90%. Reactions were performed using 1% mol of DDM as chain transfer agent and at a scale of 10 g of initial monomers.

Polymer^a	M _n ^b (g mol⁻¹)	Đ ^b	T _g (°C)	WCA (°)
pDEGMA^c	15 020	1.78	−38	40.6 ± 1.8
pTEGMA	17 290	2.10	−51	19.5 ± 1.8
pDEGEEA	7210	3.23	−55	28.6 ± 1.8
pAODMBA^d	5100^c	—	85	73.0 ± 1.7
pmMAOES	5000	1.30	11	49.0 ± 1.5
piDMA	25 380	1.68	−41	93.0 ± 1.5
piBoA	9833	1.42	92	99.0 ± 3.0

Corresponding data for polymers prepared by photo-initiated free radical-polymerization are available in Vallieres et al.²⁰

M _n and Đ were calculated by GPC.

Full monomer names and structures are given in Fig. S1.†

M _n of pAODMBA was calculated via¹H-NMR due to the poor solubility of this polymer in THF.

M n, Đ, and the physical characterisation of the thermally synthesised polymers (Tg and WCA). Conversions of all the obtained polymers were >90%. Reactions were performed using 1% mol of DDM as chain transfer agent and at a scale of 10 g of initial monomers.