Synthesis, crystal structure and Hirshfeld analysis of trans-bis­{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl­idene]hydrazinecarbo­thio­amidato-κ2 N 1,S}palladium(II)

. 2023 Oct 5;79(Pt 11):993–998. doi: 10.1107/S2056989023008654

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.0320 (9)	0.0589 (11)	0.0314 (9)	−0.0018 (8)	0.0020 (7)	−0.0014 (8)
C2	0.0327 (9)	0.0625 (12)	0.0337 (9)	−0.0045 (8)	−0.0002 (7)	0.0005 (8)
C3	0.0337 (9)	0.0606 (12)	0.0358 (9)	−0.0037 (9)	0.0015 (7)	0.0006 (9)
C4	0.0326 (9)	0.0575 (12)	0.0407 (10)	−0.0026 (8)	0.0018 (7)	0.0101 (9)
C5	0.0445 (12)	0.0656 (14)	0.0596 (13)	−0.0060 (10)	−0.0040 (10)	0.0032 (11)
C6	0.0551 (15)	0.0816 (18)	0.0838 (18)	−0.0223 (14)	−0.0209 (14)	0.0151 (15)
C7	0.0348 (12)	0.094 (2)	0.100 (2)	−0.0080 (13)	−0.0040 (13)	0.0419 (18)
C8	0.0416 (13)	0.097 (2)	0.0858 (19)	0.0078 (13)	0.0206 (13)	0.0207 (17)
C9	0.0445 (12)	0.0805 (17)	0.0594 (14)	−0.0030 (11)	0.0151 (10)	−0.0011 (12)
C10	0.0314 (9)	0.0475 (10)	0.0343 (9)	0.0002 (7)	0.0017 (7)	−0.0005 (7)
C11	0.0351 (9)	0.0486 (10)	0.0354 (9)	0.0000 (8)	−0.0029 (7)	0.0001 (8)
C12	0.0446 (11)	0.0557 (12)	0.0396 (10)	−0.0024 (9)	0.0016 (8)	−0.0032 (9)
C13	0.0578 (13)	0.0596 (13)	0.0499 (12)	−0.0054 (11)	−0.0067 (10)	−0.0103 (10)
C14	0.0443 (12)	0.0655 (14)	0.0650 (14)	−0.0103 (10)	−0.0128 (10)	−0.0005 (11)
C15	0.0341 (10)	0.0826 (17)	0.0624 (14)	−0.0034 (11)	0.0010 (10)	−0.0032 (12)
C16	0.0361 (10)	0.0735 (14)	0.0453 (11)	0.0009 (10)	0.0016 (8)	−0.0096 (10)
C17	0.0360 (9)	0.0542 (11)	0.0347 (9)	−0.0016 (8)	0.0036 (7)	−0.0037 (8)
C18	0.0356 (9)	0.0542 (11)	0.0392 (10)	−0.0007 (8)	0.0053 (8)	−0.0008 (8)
C19	0.0413 (10)	0.0586 (12)	0.0420 (10)	−0.0018 (9)	0.0078 (8)	−0.0009 (9)
C20	0.0390 (10)	0.0505 (11)	0.0471 (11)	0.0018 (8)	0.0116 (8)	0.0071 (9)
C21	0.0415 (11)	0.0609 (13)	0.0516 (12)	0.0024 (10)	0.0072 (9)	0.0081 (10)
C22	0.0468 (13)	0.0740 (16)	0.0722 (16)	−0.0050 (12)	−0.0071 (11)	0.0167 (13)
C23	0.0379 (12)	0.0804 (18)	0.096 (2)	0.0040 (12)	0.0149 (13)	0.0283 (16)
C24	0.0539 (14)	0.0804 (18)	0.089 (2)	0.0055 (13)	0.0362 (14)	0.0086 (16)
C25	0.0539 (14)	0.0782 (16)	0.0645 (15)	−0.0027 (12)	0.0246 (11)	−0.0050 (13)
C26	0.0315 (9)	0.0554 (11)	0.0351 (9)	−0.0013 (8)	0.0021 (7)	−0.0016 (8)
C27	0.0323 (9)	0.0553 (12)	0.0488 (11)	0.0009 (8)	−0.0040 (8)	−0.0101 (9)
C28	0.0631 (15)	0.0751 (16)	0.0582 (14)	−0.0127 (13)	−0.0205 (12)	0.0074 (12)
C29	0.084 (2)	0.095 (2)	0.083 (2)	−0.0132 (18)	−0.0477 (17)	0.0046 (17)
C30	0.0520 (15)	0.089 (2)	0.109 (2)	−0.0128 (14)	−0.0269 (16)	−0.0201 (18)
C31	0.0566 (15)	0.087 (2)	0.098 (2)	−0.0283 (14)	0.0074 (15)	−0.0243 (17)
C32	0.0520 (13)	0.0787 (16)	0.0592 (14)	−0.0154 (12)	0.0031 (11)	−0.0121 (12)
N1	0.0299 (7)	0.0523 (9)	0.0303 (7)	−0.0014 (6)	0.0009 (6)	−0.0023 (6)
N2	0.0324 (8)	0.0645 (10)	0.0316 (8)	−0.0058 (7)	0.0017 (6)	−0.0059 (7)
N3	0.0348 (8)	0.0659 (11)	0.0319 (8)	−0.0070 (8)	0.0045 (6)	−0.0067 (7)
N4	0.0304 (7)	0.0496 (9)	0.0349 (8)	−0.0023 (7)	0.0030 (6)	−0.0023 (7)
N5	0.0322 (8)	0.0646 (11)	0.0342 (8)	−0.0057 (7)	0.0027 (6)	−0.0055 (7)
N6	0.0341 (8)	0.0878 (14)	0.0346 (8)	−0.0110 (9)	0.0028 (7)	−0.0081 (8)
Pd1	0.02574 (7)	0.04563 (8)	0.03007 (7)	−0.00040 (5)	0.00212 (5)	−0.00124 (5)
S1	0.0344 (2)	0.0749 (3)	0.0349 (2)	−0.0119 (2)	0.00699 (18)	−0.0100 (2)
S2	0.0275 (2)	0.0866 (4)	0.0319 (2)	−0.0068 (2)	0.00370 (17)	−0.0071 (2)