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. 2023 Nov 6;14:7139. doi: 10.1038/s41467-023-43013-8

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© The Author(s) 2023

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 3 — A ¹H NMR spectra of E-3 in DMSO-d₆ (10 mM, 25 °C, Ai) upon irradiation with 365 nm (Aii) and 450 nm (Aiii) light, with multiple cycles of bidirectional switching in the inset. B Absorbance spectra of irradiation of E-3 in DMSO (60 μM) with 365 nm light and then 450 nm light. C Calculated NBO orbitals and stabilization energies (kcal/mol) of n→σ* interactions for chalcogen bond in Z-3.