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(a) Schematic illustration of the FeIII to Zr-oxo cluster charge transfer process in the FeIII-decorated Zr9 node (Zr: violet, O: red, Fe: orange; Cl: green). (b) Generation of reaction intermediates in the presence of water and under anhydrous conditions. (c) Proposed mechanism for the photocatalytic oxidation of toluene.
