Table 1. Toluene Oxidation under Different Conditions^a.

entry	catalyst	H2O/μL	t/h	conversionb	selectivityb (A/B/C)
1	NPF-520-FeIII	0	8	100	0/100/0
2	NPF-520-FeIII	0	24	100	0/100/0
3	NPF-520-FeIII	20	8	41	0/94/6
4	NPF-520-FeIII	100	6	100	0/0/100
5c	NPF-520-FeIII	0	8	0
6c	NPF-520-FeIII	100	6	0
7	NPF-520	0	12	0
8	NPF-520	100	12	0
9	FeCl3	0	12	0
10	FeCl3	100	12	0
11	UiO-66-FeIII	0	12	0
12	UiO-69-FeIII	0	12	4	0/100/0
13	UiO-66-FeIII	100	12	6	0/36/64
14	UiO-69-FeIII	100	12	12	0/18/82

^aReaction conditions: 5 μL of toluene, 1 mL of MeCN, 5 mol % catalyst (based on Fe^III), 395 nm blue LED photoreactor, 1 atm O₂.

^bDetermined by GC/GC-MS.

^cWithout O₂.