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. 2023 Oct 24;52(22):7848–7948. doi: 10.1039/d0cs00936a

Fig. 47. Exciton chirality inversion and delocalization in DNA-templated organic semiconductor dimer assemblies. (A) Structures of the two pairs of dimers of bis(chloroindolenine) SQ dye that enabled strongly coupled molecular excitons of opposite chirality in solution as seen in the CD spectra. Reproduced with permission from ref. 379 Copyright 2022 American Chemical Society. (B) Octaniline-DNA compositional monomer spontaneously assembled into the chiral dimer by adding triggering DNA strand. (C) Absorbance and CD spectral theoretical fits. Experimental data sets are shown as black lines, while theoretical fits are given as red curves. Reproduced with permission from ref. 380 Copyright 2022 American Chemical Society.

Fig. 47