Table 2. Calorimetric Data Extracted from Figure 3 for R/S PHB-38K, PCL-22K PHB39-b-PCL61, and P(HB72-ran-CL28).
| R/S PHB-38K | PCL-22K | PHB39-b-PCL61 | P(HB72-ran-CL28) | |
|---|---|---|---|---|
| Tc/cc (°C) | 78.0 | 28.0 | 14.8 (PCL block) | 78.3 |
| 71.4 (PHB block) | ||||
| ΔHc/cc (J/g) | 60 | 60 | 22 (PCL block) | 37 |
| 22(PHB block) | ||||
| Tm (°C) | 151.8/168.5 | 58.9 | 51.2 (PCL block) | 126.2/146.5 |
| 164.0 (PHB block) | ||||
| ΔHm (J/g) | 14/87 | 60 | 21 (PCL block) | 32 |
| 27 (PHB block) | ||||
| xc,25 °C (%) | 41 | 43 | 25 (PCL) | 0 (PHB) |
| 0 (PHB) | 0 (PCL) | |||
| xc,100 °C (%) | 41 | 0 | 0 (PCL) | 0 (PCL) |
| 46 (PHB) | 22 (PHB) | |||
| Tg (°C) | 1.4 | –50.6 | –3.9 | –14.0 |
| % PCL | 0 | 100 | 61 | 28 |
| Mn (kDa) | 38 | 22 | 36 (Total) | 75 |
| 14 (PHB) | ||||
| 22 (PCL) |