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. 2023 Nov 1;62(45):18338–18356. doi: 10.1021/acs.inorgchem.3c02526

Table 10. Catalytic Activities of Complexes with H2O2 (Catalyst:H2O2 = 1:100).

substrate (mmol) product complex 1a
complex 2a
complex 3a
complex 4a
    TONa efficiencyb TON efficiency TON efficiency TON efficiency
thioanisole (0.25) thioanisole oxide 1.8 1.8 2.5 2.5 27.8 27.8 27 27
9,10-DHA (0.05) anthracene 15.9 15.9 23.2 23.2 28.2 28.2 26.7 26.7
1,4-CHD benzene 16.5 16.5 22.4 22.4 54.4 54.4 49.5 49.5
triphenylmethane (0.25) triphenylmethanol 22.8   30.8 30.8 8 8 10 10
cumene (0.25) 2-phenyl-2-propanol         6.9 7.49 12.6 14.2
  acetophenone         0.59   1.6  
ethylbenzene (0.25) 1-phenylethanol 5.3 12.33 7 16.02 5.42 13.24 4.4 12.8
  1-acetophenone 7.03   9.02   7.82   8.4  
toluene (0.25) benzaldehyde 4 4 6.1 6.1 4.5 4.5 3.5 3.5
cyclohexane (0.5) cyclohexanol 4.38 8.98 6.2 13.4 5.86 12.33 5.6 11.87
  cyclohexanone 4.6   7.2   6.47   6.27  
a

Turnover number (TON) = mol of product/mol of catalyst.

b

Efficiency (%) = moles of total products/mol of oxidant ×100.