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. 2023 Nov 1;62(45):18338–18356. doi: 10.1021/acs.inorgchem.3c02526

Table 9. Catalytic Activities of Complexes 14b with IBX Ester (Catalyst:IBX Ester = 1:10).

substrate (mmol) product complex 1a
complex 2a
complex 3a
complex 4a
    TONa efficiencyb TON efficiency TON efficiency TON efficiency
thioanisole (0.25) thioanisole oxide 9.2 92 10 100 10 100 10 100
9,10-DHA (0.05) anthracene 9.6 96 10 100 10 100 9.6 96
1,4-CHD (0.25) benzene 9.3 93 9.7 97 10 100 10 100
triphenylmethane (0.25) triphenylmethanol 9.8 98 10 100 9.3 93 8.65 86.5
cumene (0.25) 2-phenyl-2-propanol         1.66 30.7 3.56 57.7
  acetophenone         1.41   2.21  
ethylbenzene (0.25) 1-phenylethanol 0.47 19.3 0.57 24 0.75 29.1 0.71 32.1
  1-acetophenone 1.46   1.826 2.16 2.5      
a

Turnover number (TON) = mol of product/mol of catalyst.

b

Efficiency (%) = moles of total products/mol of oxidant ×100.