Table 2. 13C NMR Data of Isolated Compounds in Pyridine.
| 3 | 9 | 7 | 8 | |
|---|---|---|---|---|
| position | cucurbitacin E | cucurbitacin E 2-O-β-d-glucopyranoside | neocucurbitan A | neocucurbitan B |
| 1 | 115.8, CH | 121.3, CH | 134.3, CH | 134.4, CH |
| 2 | 147.3, C | 145.3, C | ||
| 3 | 199.0, C | 198.9, C | 172.6, C | 172.6, C |
| 4 | 48.6, C | 48.9, C | 42.6, C | 42.6, C |
| 5 | 137.7, C | 135.6, C | 132.7, C | 132.7, C |
| 6 | 120.5, CH | 121.3, CH | 123.8, CH | 123.8, CH |
| 7 | 23.9, CH2 | 23.7, CH2 | 25.0, CH2 | 25.0, CH2 |
| 8 | 42.1, CH | 41.3, CH | 42.4, CH | 42.3, CH |
| 9 | 49.3, C | 48.9, C | 47.9, C | 47.8, C |
| 10 | 35.1, CH | 35.4, CH | 117.7, C | 117.6, C |
| 11 | 213.8, C | 214.6, C | 211.9, C | 211.8, C |
| 12 | 49.3, CH2 | 49.0, CH2 | 50.4, CH2 | 50.5, CH2 |
| 13 | 48.6, C | 50.6, C | 48.9, C | 51.0, C |
| 14 | 51.0, C | 48.0, C | 51.0, C | 48.9, C |
| 15 | 46.5, CH2 | 45.5, CH2 | 45.7, CH2 | 45.8, CH2 |
| 16 | 70.7, CH | 71.2, CH | 70.4, CH | 70.2, CH |
| 17 | 60.0, CH | 58.2, CH | 59.8, CH | 59.3, CH |
| 18 | 20.6, CH3 | 20.2, CH3 | 20.4, CH3 | 20.4, CH3 |
| 19 | 20.1, CH3 | 20.0, CH3 | 25.1, CH3 | 25.2, CH3 |
| 20 | 79.8, C | 78.2, C | 79.6, C | 79.2, C |
| 21 | 25.6, CH3 | 24.0, CH3 | 25.4, CH3 | 25.4, CH3 |
| 22 | 204.4, C | 202.6, C | 204.2, C | 204.2,C |
| 23 | 122.5, CH | 120.4, CH | 122.4, CH | 120.8, CH |
| 24 | 150.2, CH | 152.0, CH | 150.3, CH | 155.7, CH |
| 25 | 79.7, C | 79.4, C | 79.8, C | 70.2, C |
| 26 | 26.2, CH3 | 25.9, CH3 | 26.2, CH3 | 29.7, CH3 |
| 27 | 26.5, CH3 | 26.5, CH3 | 26.6, CH3 | 30.0, CH3 |
| 28 | 18.4, CH3 | 19.9, CH3 | 18.1, CH3 | 18.0, CH3 |
| 29 | 28.0, CH3 | 27.9, CH3 | 28.5, CH3 | 22.4, CH3 |
| 30 | 20.8, CH3 | 18.2, CH3 | 22.3, CH3 | 28.5, CH3 |
| 31 | 169.8, C | 170.4, C | 169.8, C | |
| 32 | 21.7, CH3 | 22.0, CH3 | 21.7, CH3 | |
| 1′-Oglc | 100.5, CH | |||
| 2′ | 72.3, CH | |||
| 3′ | 75.8, CH | |||
| 4′ | 69.3, CH | |||
| 5′ | 76.7, CH | |||
| 6′ | 61.5, CH2 |