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. 2023 Jul 3;57(46):18080–18090. doi: 10.1021/acs.est.3c00293

Table 5. XPS Characterizationa.

catalyst Mn4+/(Mn4+ + Mn3+) (%) Fe3+/(Fe2+ + Fe3+) (%) Ni3+/(Ni2+ + Ni3+) (%) Oβ/(Oβ + Oα + Oγ) (%)
Fe0.4Mn0.15Ni0.45 36.53 46.36 40.96 26.81
Fe0.2Mn0.2Ni0.6 33.84 51.38 43.09 18.17
Fe0.2Mn0.6Ni0.2 14.67 46.04 41.93 13.62
Fe0.319Mn0.206Ni0.475 34.28 44.89 42.17 22.32
a

Note that catalyst Fe0.319Mn0.206Ni0.475 was identified from the second round of iteration (Figure S4 of the Supporting Information), and other three catalysts were identified from the first round of iteration.