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Electrochemical data, HOMO and LUMO energies, and energy gaps obtained by cyclic voltammetry and optical measurements.
| Sample | E ox (V) irreversible | E red (V) irreversible | E HOMO (eV) | E LUMO (eV) | ΔE CV (eV) | ΔE Opt (eV) |
|---|---|---|---|---|---|---|
| D1 | 1.0 | −2.1 | −5.3 | −2.2 | 3.1 | 2.9 |
| D2 | 0.9 | −2.1 | −5.2 | −2.2 | 3.0 | 2.8 |
