Table 1.
1H and 13C NMR data of 6 (acquired in CDCl3).
| Position | 6 | Position | 6 | ||
|---|---|---|---|---|---|
| δC, Type | δH (J in Hz) | δC, Type | δH (J in Hz) | ||
| 1 | 58.1, CH2 | 3.85, ddd (11.0, 6.0, 3.8) 3.93, ddd (11.0, 7.2, 3.4) |
14 | 37.3, CH | 1.14, m |
| 2 | 41.3, CH2 | 2.69, ddd (18.9, 6.0, 3.4) 2.88, ddd (18.9, 7.2, 3.8) |
15 | 24.6, CH2 | 0.75, overlap 1.48, d (7.0) |
| 3 | 215.7, C | 16 | 12.7, CH3 | 0.77, d (4.2) | |
| 4 | 52.6, C | 17 | 19.4, CH3 | 0.95, d (6.7) | |
| 5 | 43.1, CH | 1.97, d (4.1) | 18 | 22.4, CH3 | 0.60, d (5.8) |
| 6 | 31.6, CH | 1.62, overlap | 19 | 19.5, CH3 | 1.28, s |
| 7 | 39.1, CH2 | 1.59, overlap 1.89, dd (12.1, 2.8) |
1’ | 167.5, C | |
| 8 | 73.6, CH | 5.30, m | 2’ | 119.6, CH | 6.01, s |
| 9 | 74.4, CH | 3.58, dd (10.9, 3.2) | 3’ | 151.9, C | |
| 10 | 40.4, CH | 2.12, d (10.9) | 4’ | 39.8, CH2 | 3.63, d (14.6) 3.77, d (14.6) |
| 11 | 125.7, CH | 6.05, d (10.6) | 5’ | 172.8, C | |
| 12 | 124.1, CH | 5.72, ddd (10.6, 4.7, 2.6) | 6’ | 26.2, CH3 | 2.06, s |
| 13 | 52.5, CH | 1.97, d (4.7) | |||