Table 4.
1H and 13C NMR data of 1 and 2 (acquired in CD3OD).
| Position | 1 | 2 | ||
|---|---|---|---|---|
| δC, Type | δH (J in Hz) | δC, Type | δH (J in Hz) | |
| 2 | 168.0, C | 165.5, C | ||
| 3 | 117.8, C | 121.6, C | ||
| 4 | 182.1, C | 178.2, C | ||
| 4a | 105.1, C | 109.0, C | ||
| 5 | 163.2, C | 162.2, C | ||
| 6 | 99.3, CH | 6.32, d (2.2) | 97.1, CH | 6.50, d (2.3) |
| 7 | 167.4, C | 166.1, C | ||
| 8 | 93.3, CH | 6.49, d (2.2) | 93.9, CH | 6.59, d (2.3) |
| 8a | 159.0, C | 161.1, C | ||
| 9 | 56.5, CH3 | 3.86, s | 56.4, CH3 | 3.91, s |
| 10 | 18.1, CH3 | 2.52, s | 17.8, CH3 | 2.48, s |
| 11 | 55.5, CH2 | 4.57, s | ||
| 12 | 56.5, CH3 | 3.90, s | ||
| 2′ | 180.2, C | |||
| 3′ | 69.5, CH | 4.90, dd (9.3, 5.9) | ||
| 4′ | 36.2, CH2 | 2.48, m 2.75, ddd (13.5, 9.3, 4.1) |
||
| 5′ | 74.9, CH | 5.73, dd (9.9, 4.1) | ||