Table 5.
1H and 13C NMR data of 4 and 5 (acquired in DMSO-d6).
| Position | 4 | 5 | ||
|---|---|---|---|---|
| δC, Type | δH (J in Hz) | δC, Type | δH (J in Hz) | |
| 1 | 106.9, CH | 6.12, d (1.9) | 106.9, CH | 6.12, d (2.1) |
| 2 | 158.5, C | 158.5, C | ||
| 3 | 101.2, CH | 6.10, d (1.9) | 101.2, CH | 6.10, d (2.1) |
| 4 | 158.5, C | 158.5, C | ||
| 5 | 106.9, CH | 6.12, d (1.9) | 106.9, CH | 6.12, d (2.1) |
| 6 | 137.5, C | 137.5, C | ||
| 7 | 38.7, CH2 | 3.65, s | 38.8, CH2 | 3.64, s |
| 8 | 167.6, C | 167.7, C | ||
| 9 | 113.2, CH | 6.04, d (2.3) | 113.3, CH | 6.04, d (2.3) |
| 10 | 178.7, C | 178.7, C | ||
| 11 | 113.2, CH | 6.07, dd (2.3, 0.9) | 114.0, CH | 6.05, d (2.3) |
| 12 | 165.8, C | 166.9, C | ||
| 13 | 19.2, CH3 | 2.20, d (0.9) | 42.6, CH2 | 2.52, d (3.7) |
| 14 | 64.0, CH | 3.90, m | ||
| 15 | 23.2, CH3 | 1.06, d (6.1) | ||
| 2-OH | 9.22, s | 9.22, s | ||
| 4-OH | 9.22, s | 9.22, s | ||
| 14-OH | 4.80, d (5.1) | |||