Table 2.
Carbonyl stretching frequencies (cm−1) from the SEC measurements.
| Complex | Solvent | Native State | 1e Reduction State | 2e Reduction State |
|---|---|---|---|---|
| 1 | MeCN | 2026, 1933, 1922 | 1973, 1931, 1878, 1852 | 1909, 1811 |
| DMA | 2021, 1930, 1912 | 1969, 1927, 1875, 1853 | 1907, 1810 | |
| 2 | MeCN | 2021, 1915, 1897 | 1997, 1886, 1866 | 1986, 1850 |
| DMA | 2016, 1912, 1890 | 1992, 1879, 1860 | 1981, 1860 | |
| 3 | MeCN | 2026, 1932, 1921 | 1974, 1932, 1878, 1854 | 1917, 1816 |
| DMA | 2021, 1930, 1912 | 1972, 1929, 1877, 1855 | 1916, 1815 | |
| 4 | MeCN | 2014, 1903, 1883 | 1998, 1882, 1864 | 1986, 1862 |
| DMA | 2009, 1899, 1877 | not observed | 1980, 1859 |