The application of the present method to water and beverage, soil, human hair, and cosmetic samples for the determination of selenium ions.
| Samples | Added [ng mL−1] | Founda [ng mL−1] | Recovery (%) | t-testb | F-valueb | |
|---|---|---|---|---|---|---|
| Sensor | ETAAS | |||||
| Tap water | — | 0.40 ± 0.06 | 0.45 ± 0.85 | |||
| 40 | 40.75 ± 0.08 | 41.00 ± 0.77 | 100.87 | 1.86 | ||
| 80 | 79.60 ± 0.13 | 81.00 ± 1.05 | 99.00 | 3.77 | ||
| Mineral water | — | 0.30 ± 0.07 | 0.27 ± 1.15 | |||
| 50 | 50.50 ± 0.11 | 49.80 ± 1.20 | 100.40 | 1.67 | ||
| 100 | 99.90 ± 0.18 | 101.0 ± 0.95 | 99.60 | 3.93 | ||
| Underground water | — | 0.65 ± 0.14 | 0.60 ± 0.85 | |||
| 60 | 60.35 ± 0.09 | 61.0 ± 1.05 | 99.50 | 2.11 | ||
| 120 | 121.0 ± 0.10 | 120.2 ± 1.30 | 100.29 | 4.05 | ||
| Rain water | — | 0.25 ± 0.15 | 0.25 ± 0.90 | |||
| 70 | 69.90 ± 0.07 | 70.70 ± 0.80 | 99.50 | 1.83 | ||
| 140 | 140.6 ± 0.12 | 139.5 ± 1.00 | 100.25 | 3.93 | ||
| River water | — | 0.55 ± 0.06 | 0.50 ± 1.10 | |||
| 80 | 80.05 ± 0.08 | 81.00 ± 1.25 | 99.94 | 1.47 | ||
| 160 | 161.3 ± 0.13 | 159.6 ± 0.75 | 100.47 | 3.73 | ||
| Ice tea | — | 1.00 ± 0.08 | 1.00 ± 1.15 | — | ||
| 55 | 55.25 ± 0.16 | 57.2 ± 0.95 | 98.66 | 4.04 | ||
| 110 | 113.2 ± 0.20 | 108.5 ± 0.85 | 101.98 | 1.97 | ||
| Mixed fruit juice | — | 75.5 ± 0.25 | 75.0 ± 1.20 | |||
| 50 | 126.5 ± 0.21 | 124.2 ± 1.45 | 100.80 | 3.78 | ||
| 100 | 173.7 ± 0.13 | 177.0 ± 0.95 | 98.97 | 2.03 | ||
| Fresh cabbagec | — | 1.12 ± 0.07 | 1.15 ± 1.05 | |||
| 75 | 77.00 ± 0.11 | 74.65 ± 1.30 | 101.16 | 1.88 | ||
| 150 | 149.7 ± 0.17 | 153.0 ± 1.55 | 99.06 | 3.75 | ||
| Soilc | — | 0.25 ± 0.09 | 0.25 ± 0.75 | |||
| 65 | 65.75 ± 0.14 | 64.30 ± 1.00 | 100.77 | 2.14 | ||
| 130 | 128.8 ± 0.19 | 131.8 ± 1.35 | 98.88 | 4.16 | ||
| Cosmetic preparation (5.0 g lipstick) | — | 253.5 ± 0.04 | 254.0 ± 1.55 | |||
| 100 | 365.7 ± 0.11 | 335.8 ± 2.05 | 103.45 | 2.04 | ||
| 175 | 415.4 ± 0.13 | 435.5 ± 1.85 | 96.90 | 3.89 | ||
| — | 225.8 ± 0.15 | 220.8 ± 1.65 | ||||
| Human hair (0.5 g) | 65 | 280.5 ± 0.18 | 300.5 ± 0.19 | 98.15 | 1.83 | |
| 130 | 360.7 ± 0.20 | 330.4 ± 0.19 | 101.38 | 3.65 | ||
Mean ± SD.
Theoretical values for t and F values at 95% confidence level for five degrees of freedom are 2.57 and 5.05, respectively.
μg kg−1.