Skip to main content
. 2023 Nov 27;13(49):34618–34629. doi: 10.1039/d3ra05308c

The application of the present method to water and beverage, soil, human hair, and cosmetic samples for the determination of selenium ions.

Samples Added [ng mL−1] Founda [ng mL−1] Recovery (%) t-testb F-valueb
Sensor ETAAS
Tap water 0.40 ± 0.06 0.45 ± 0.85
40 40.75 ± 0.08 41.00 ± 0.77 100.87 1.86
80 79.60 ± 0.13 81.00 ± 1.05 99.00 3.77
Mineral water 0.30 ± 0.07 0.27 ± 1.15
50 50.50 ± 0.11 49.80 ± 1.20 100.40 1.67
100 99.90 ± 0.18 101.0 ± 0.95 99.60 3.93
Underground water 0.65 ± 0.14 0.60 ± 0.85
60 60.35 ± 0.09 61.0 ± 1.05 99.50 2.11
120 121.0 ± 0.10 120.2 ± 1.30 100.29 4.05
Rain water 0.25 ± 0.15 0.25 ± 0.90
70 69.90 ± 0.07 70.70 ± 0.80 99.50 1.83
140 140.6 ± 0.12 139.5 ± 1.00 100.25 3.93
River water 0.55 ± 0.06 0.50 ± 1.10
80 80.05 ± 0.08 81.00 ± 1.25 99.94 1.47
160 161.3 ± 0.13 159.6 ± 0.75 100.47 3.73
Ice tea 1.00 ± 0.08 1.00 ± 1.15
55 55.25 ± 0.16 57.2 ± 0.95 98.66 4.04
110 113.2 ± 0.20 108.5 ± 0.85 101.98 1.97
Mixed fruit juice 75.5 ± 0.25 75.0 ± 1.20
50 126.5 ± 0.21 124.2 ± 1.45 100.80 3.78
100 173.7 ± 0.13 177.0 ± 0.95 98.97 2.03
Fresh cabbagec 1.12 ± 0.07 1.15 ± 1.05
75 77.00 ± 0.11 74.65 ± 1.30 101.16 1.88
150 149.7 ± 0.17 153.0 ± 1.55 99.06 3.75
Soilc 0.25 ± 0.09 0.25 ± 0.75
65 65.75 ± 0.14 64.30 ± 1.00 100.77 2.14
130 128.8 ± 0.19 131.8 ± 1.35 98.88 4.16
Cosmetic preparation (5.0 g lipstick) 253.5 ± 0.04 254.0 ± 1.55
100 365.7 ± 0.11 335.8 ± 2.05 103.45 2.04
175 415.4 ± 0.13 435.5 ± 1.85 96.90 3.89
225.8 ± 0.15 220.8 ± 1.65
Human hair (0.5 g) 65 280.5 ± 0.18 300.5 ± 0.19 98.15 1.83
130 360.7 ± 0.20 330.4 ± 0.19 101.38 3.65
a

Mean ± SD.

b

Theoretical values for t and F values at 95% confidence level for five degrees of freedom are 2.57 and 5.05, respectively.

c

μg kg−1.