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. 2023 Nov 28;13(49):34733–34738. doi: 10.1039/d3ra06530h

One-pot reductive amidation of nitroarenes in the presence of acetic anhydride using β-CD-TiO2 under blue LED irradiation.

Entry Substrate Product Yielda (%)
1 graphic file with name d3ra06530h-u40.jpg graphic file with name d3ra06530h-u41.jpg 97
2 graphic file with name d3ra06530h-u42.jpg graphic file with name d3ra06530h-u43.jpg 90
3 graphic file with name d3ra06530h-u44.jpg graphic file with name d3ra06530h-u45.jpg 98
4 graphic file with name d3ra06530h-u46.jpg graphic file with name d3ra06530h-u47.jpg 95
5 graphic file with name d3ra06530h-u48.jpg graphic file with name d3ra06530h-u49.jpg 98
6 graphic file with name d3ra06530h-u50.jpg graphic file with name d3ra06530h-u51.jpg 84
7 graphic file with name d3ra06530h-u52.jpg graphic file with name d3ra06530h-u53.jpg 94
8 graphic file with name d3ra06530h-u54.jpg graphic file with name d3ra06530h-u55.jpg 91
9 graphic file with name d3ra06530h-u56.jpg graphic file with name d3ra06530h-u57.jpg 85
a

Reaction condition: TiO2-P25 (7.5 mg), nitro compound (1.2 mmol), irradiation with blue LED (10 W), Na2S (3.6 mmol), acetic android (3.6 mmol), irradiation time, 12 h.