Table 3. Magnetic Susceptibility Data for of [CnC1Im][FeCl3X] and [CnC1Im]3[MCl3X3] Series PILs.
compound | χm (m3 mol–1 × 10–7) | χg (m3 kg–1) × 10–7 | χ × 10–4 | μeff (μb) |
---|---|---|---|---|
[C4C1Im][FeCl4]* | 0.141 | 0.419 | 0.586 | 5.75 |
[C4C1Im][FeCl4] | 0.158 | 0.469 | 0.648 | 6.09 |
[C6C1Im][FeCl4] | 0.157 | 0.430 | 0.576 | 6.07 |
[C8C1Im][FeCl4] | 0.153 | 0.389 | 0.479 | 5.99 |
[C4C1Im][FeCl3Br] | 0.143 | 0.375 | 0.564 | 5.79 |
[C6C1Im][FeCl3Br] | 0.153 | 0.374 | 0.530 | 5.99 |
[C8C1Im][FeCl3Br] | 0.131 | 0.299 | 0.412 | 5.54 |
[C4C1Im]3[HoCl6] | 0.602 | 0.758 | 1.426 | 11.88 |
[C6C1Im]3[HoCl6] | 0.881 | 1.002 | 1.676 | 14.37 |
[C8C1Im]3[HoCl6] | 1.064 | 1.105 | 1.759 | 15.80 |
[C4C1Im]3[HoCl3Br3] | 0.899 | 0.968 | 1.752 | 14.52 |
[C6C1Im]3[HoCl3Br3] | 0.988 | 0.976 | 1.599 | 15.22 |
[C8C1Im]3[HoCl3Br3] | 0.986 | 0.899 | 1.484 | 15.21 |
[C4C1Im]3[DyCl6] | 0.881 | 1.112 | 2.067 | 14.37 |
[C6C1Im]3[DyCl6] | 0.910 | 1.038 | 1.816 | 14.61 |
[C8C1Im]3[DyCl6] | 0.865 | 0.901 | 1.425 | 14.24 |
[C4C1Im]3[DyCl3Br3] | 0.863 | 0.932 | 1.650 | 14.23 |
[C6C1Im]3[DyCl3Br3] | 0.820 | 0.812 | 1.243 | 13.87 |
[C8C1Im]3[DyCl3Br3] | 0.682 | 0.623 | 0.944 | 12.65 |
[C4C1Im]3[GdCl6] | 0.363 | 0.461 | 0.749 | 9.23 |
[C6C1Im]3[GdCl6] | 0.492 | 0.565 | 0.838 | 10.74 |
[C8C1Im]3[GdCl6] | 0.562 | 0.588 | 1.014 | 11.48 |
[C4C1Im]3[GdCl3Br3] | 0.540 | 0.587 | 1.011 | 11.25 |
[C6C1Im]3[GdCl3Br3] | 0.492 | 0.490 | 0.780 | 10.74 |
[C8C1Im]3[GdCl3Br3] | 0.585 | 0.537 | 0.915 | 11.71 |