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. 2023 Oct 25;1(9):555–564. doi: 10.1021/prechem.3c00082

Table 1. Long-Wavelength Extinction Coefficients (ε) and Fluorescence Quantum Yields (FQYs), Obtained from Steady-State Absorption and Fluorescence Measurements.

Compound Solvent λmax/nm ε/M–1 cm–1 FQY/%
Lpc toluene 633 40,700 35.3
THF 660 34,700 23.4
BN 670 37,000 9.1
Pt(Lpc)(Lref)Cl2 toluene 676 31,800 9.3
THF 672 31,900 3.0
BN 685 28,800 0.7
Pd(Lpc)(Lref)Cl2 toluene 675 35,300 12.5
THF 671 35,800 7.4
BN 684 27,400 3.3
Pt(Lpc)2Cl2 toluene 678 68,500 6.9
THF 674 71,500 2.6
BN 687 51,400 0.6
Pd(Lpc)2Cl2 toluene 677 67,600 10.1
THF 671 61,700 6.0
BN 681 46,400 2.5