Table 1. Long-Wavelength Extinction Coefficients (ε) and Fluorescence Quantum Yields (FQYs), Obtained from Steady-State Absorption and Fluorescence Measurements.
Compound | Solvent | λmax/nm | ε/M–1 cm–1 | FQY/% |
---|---|---|---|---|
Lpc | toluene | 633 | 40,700 | 35.3 |
THF | 660 | 34,700 | 23.4 | |
BN | 670 | 37,000 | 9.1 | |
Pt(Lpc)(Lref)Cl2 | toluene | 676 | 31,800 | 9.3 |
THF | 672 | 31,900 | 3.0 | |
BN | 685 | 28,800 | 0.7 | |
Pd(Lpc)(Lref)Cl2 | toluene | 675 | 35,300 | 12.5 |
THF | 671 | 35,800 | 7.4 | |
BN | 684 | 27,400 | 3.3 | |
Pt(Lpc)2Cl2 | toluene | 678 | 68,500 | 6.9 |
THF | 674 | 71,500 | 2.6 | |
BN | 687 | 51,400 | 0.6 | |
Pd(Lpc)2Cl2 | toluene | 677 | 67,600 | 10.1 |
THF | 671 | 61,700 | 6.0 | |
BN | 681 | 46,400 | 2.5 |