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. 2023 Oct 24;14(46):13508–13517. doi: 10.1039/d3sc04903e

Emission enhancement factors (I/Io) and lifetimes (τ) of complexes 1–4 (10 μM) upon incubation with TCO-OH (100 μM) for 12 h in aerated H2O/DMSO (99 : 1, v/v) at 298 K.

Complex I/Ioa τ b (μs)
1 40.9 0.47
2 28.9 1.02
3 56.2 0.95
4 11.4 0.90
a

I o and I are the emission intensities of the complexes in the absence and presence of TCO-OH, respectively.

b

The emission lifetimes of the complexes after incubation with TCO-OH for 12 h. In the absence of TCO-OH, the emission lifetimes of the complexes could not be determined accurately.