Figure 1.
(a) The photoacoustic response of gold nanorods at low laser fluence is produced by the heating of the nanorods and surrounding fluid. If the physical properties of the particle and fluid are not temperature dependent, then a linear relationship between fluence and photoacoustic response is expected. (b) In surface modified silica coated nanorods, vaporization of the liquid surrounding the nanorods leads to bubble formation and a highly nonlinear photoacoustic response. Schematics are not drawn to scale.