. 2023 Nov 13;8(47):44820–44830. doi: 10.1021/acsomega.3c06006

Table 3. Stern–Volmer Constants and Bimolecular Quenching Rate Constant, k_q, at 25 and 50 °C for Monomer Crowders^a.

	K_SV (M^–1)		k_q (M^–1 ns^–1)
crowders	25°C	50°C	25°C	50°C
dextrose	0.0415 (0.90)	–0.038 (0.74)	0.0134
sucrose	0.444 (0.96)	0.241 (1.0)	0.143	0.155
ethylene glycol	–0.0325 (0.97)	–0.040 (0.94)
1-ethyl-2-pyrrolidone	0.254 (0.92)	0.138 (0.84)	0.0819	0.0888

The bimolecular quenching rate constant, k_q, values were obtained using eq 2 with τ₀ value of 3.1 ns⁴ and 1.55 ns at 25 and at 50 °C, respectively. The goodness-of-fit (correlation coefficient) of the fitted functions are given in parentheses.

Table 3. Stern–Volmer Constants and Bimolecular Quenching Rate Constant, kq, at 25 and 50 °C for Monomer Crowdersa.

Table 3. Stern–Volmer Constants and Bimolecular Quenching Rate Constant, k_q, at 25 and 50 °C for Monomer Crowders^a.