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. 2023 Nov 16;11:1254739. doi: 10.3389/fbioe.2023.1254739

TABLE 2.

Overview of cardiac patches based on natural biomaterials and fabricated by 3D printing/bioprinting.

Technology Materials Cells Functionalization strategy Ref
Inkjet Alginate and gelatin Primary feline adult cardiomyocytes and HL1 cardiac muscle cell line - Xu et al. (2009)
Alginate Mouse fibroblasts (NIH3T3) - Christensen et al. (2015)
Extrusion based Heart-derived decellularized ECM Human cardiac progenitor cells (hCPCs) Vascular endothelial growth factor (VEGF) in the MSC laden bioink to promote neovascularization Jang et al. (2017)
Human turbinate tissue-derived mesenchymal stem cells
Non-mulberry silk fibroin Human umbilical vein endothelial cells (HUVECs)–in the bioink Carbon nanotubes for electrical conductivity Mehrotra et al. (2021)
Polyethylene glycol di-methacrylate (PEGDMA) Neonatal rat cardiomyocytes–seeding on printed structures Interleukin-10 (IL-10)-loaded GelMA microspheres with immunomodulatory activity and calcium peroxide (oxygen concentration enhancement, cell viability up to 5 days in hypoxic environment)
Gelatin methacryloyl (GelMA)
Alginate/gelatin Neonatal mouse cardiac cell spheroids or free (non-spheroid) human coronary artery endothelial cells with fibroblasts - Roche et al. (2021)
Alginate HUVECs - Delkash et al. (2021)
Egg-white
Decellularized pig omentum Neonatal rat ventricular cardiac cells Asulin et al. (2021)
Microbial transglutaminase (mTgase) crosslinked gelatin Human MSCs 3D printed line features (contact guidance) Tijore et al. (2018)
Cardiomyocytes
Type I collagen Reprogrammed human adipogenic mesenchymal stem cells to form purkinje cells - Tracy et al. (2020)
Alginate, GelMA HUVECs (in the bioink) - Zhang et al. (2016)
Neonatal rat cardiomyocytes
hiPSC-CMs
Porcine heart decellularized ECM and medical grade COLTRIX (Type-1 atelo-collagen) Neonatal rat cardiomyocytes - Das et al. (2019)
Genetically engineered multi-domain proteins (ASP - leucine zipper derived and A35m - mussel foot protein derived) - Hydrogels loaded with recombinant human follistatin-like 1 (FSTL1) (known to improve cardiac function and survival in mouse and swine models) Jiang et al. (2022)
Alginate Rat ventricular cardiomyocytes and Cardiac fibroblasts Gold nanorods for improved electrical conductivity Zhu et al. (2017)
GelMA
Fibrin-based composite hydrogel (fibrinogen, gelatin, aprotinin, glycerol, and hyaluronic acid) as bioink Neonatal rat ventricular cardiomyocytes - Wang et al. (2018)
Gelatin, glycerol, and hyaluronic acid as support (sacrificial) gel
Decellularized ECM from heart, adipose and cartilage tissues Human adipose-derived stem cells and human inferior turbinate-tissue derived mesenchymal stromal cells - Pati et al. (2014)
Rat myoblast cells (L6, ATCC CRL-1458)
Non-mulberry silk fibroin, PEGDMA, GelMA Human induced pluripotent stem cell derived cardiac spheroids - Mehrotra et al. (2020)
Alginate HUVECs and hiPSC-CMs - Maiullari et al. (2018)
Polyethylene glycol-Fibrinogen
Alginate Bone marrow mesenchymal stem cells - Liu et al. (2021)
Gelatin
Furfuryl−gelatin and fibrinogen solutions hiPSC-CMs - Anil Kumar et al. (2019)
Human cardiomyocytes (AC16 cell lines)
Methacrylated collagen (MeCol) Human coronary artery endothelial cells MeCol micropatterning, for topographical stimuli Izadifar et al. (2018)
Alginate Carbon nanotubes incorporation, for conductivity
Hyaluronic acid/gelatin Human cardiac-derived progenitor cells (hCMPCs) - Gaetani et al. (2015)
Double bioink hiPSC-CMs - Chikae et al. (2019)
-Cells, Thrombin and hyaluronic acid
-Fibrinogen and hyaluronic acid
Decellularized cardiac ECM and GelMA Human cardiac progenitor cells - Bejleri et al. (2018)
FRESH Alginate-based hydrogels (RGD modified alginate/Calcium Gluconate/Gelatin/Matrigel for the core; calcium cross-linked alginate/alginate sulfate/extracellular vesicles for the shell) Human monocytic THP-1 cells Extracellular vesicle delivery system Bar et al. (2022)
GFP expressing human fibroblasts RGD modified alginate for better cell-matrix interactions
Human or pig decellularized omenta (bioinks) hiPSC-CMs - Noor et al. (2019)
Endothelial cells laden gelatin hydrogel (sacrificial ink) hiPSC derived endothelial cells
Alginate microparticles, xhantan gum supplemented growth medium (FRESH support medium) Neonatal rat cardiac cells, HUVECs and lumen-supporting fibroblasts
Laser Decellularized cardiac ECM hiPSC-CMs, smooth muscle cells and endothelial cells - Gao et al. (2017)
UV-based GelMA/PEGDA hiPSC-CMs 4D morphing of the scaffolds driven by light-induced graded pattern of stress (solvent-activated relaxation: swelling-induced stretching and dehydration-induced bending) Cui et al. (2020)
Human mesenchymal stem cells
Human endothelial cells
GelMA or hyaluronic acid glycidyl methacrylate and PEGDA Neonatal mouse ventricular cardiomyocytes Micropatterning of the constructs for topographical stimuli Liu et al. (2020)
Soybean oil epoxidized acrylate Human bone marrow mesenchymal stem cells Micropatterning for topographical stimuli Miao et al. (2018)
4D shape changing with immersion in ethanol