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. 2023 Jan 27;57(47):18658–18667. doi: 10.1021/acs.est.2c07694

Table 2. Conditions of Ozonation Experiments with Lake Zurich Water (1.4 mgC/L DOC, 2.7 mM Alkalinity, 2 μM Bromide (spiked), 0.5 μM pCBA (spiked), 1 mM Phosphate Buffer at pH 7.6 (spiked)) and the Determined Rct (Figure 20a), the Bromate Formation Slopes Expressed As a Function of Ozone Exposure, And the Change in Bromate Formation with Regard to the Reference Conditions.

no. condition comment Rct slope (μM/(M s))a change in bromate formationb (%) reference condition
1 Lake Zurich water (unaltered) reference for low Rct 3.7 × 10–9 29.5 ± 6.8    
2 Lake Zurich water + 10 μM formate reference for high Rct 7.4 × 10–9 33.8 ± 3.9 +15 1
3 Lake Zurich water + 4 μM NH4+ NH4+ as HOBr quencher 4.3 × 10–9 18.9 ± 0.8 –36 1
4 Lake Zurich water + 7 μM NH2Cl NH2Cl as HOBr/Br quencher 5.6 × 10–9 11.8 ± 1.1 –60 1
5 Lake Zurich water + 15 μM NH2Cl NH2Cl as HOBr/Br quencher 9.9 × 10–9 7.9 ± 0.7 –73 1
–77 2
–58 3
a

Slopes were obtained from linear regression of a bromate concentration plot as a function of ozone exposure for the initial phase (Figure 4b).

b

Changes in bromate formation were obtained by comparing the slope of a condition with the slope of a reference condition specified in the last column.