Table 2. Conditions of Ozonation Experiments with Lake Zurich Water (1.4 mgC/L DOC, 2.7 mM Alkalinity, 2 μM Bromide (spiked), 0.5 μM pCBA (spiked), 1 mM Phosphate Buffer at pH 7.6 (spiked)) and the Determined Rct (Figure 20a), the Bromate Formation Slopes Expressed As a Function of Ozone Exposure, And the Change in Bromate Formation with Regard to the Reference Conditions.
no. | condition | comment | Rct | slope (μM/(M s))a | change in bromate formationb (%) | reference condition |
---|---|---|---|---|---|---|
1 | Lake Zurich water (unaltered) | reference for low Rct | 3.7 × 10–9 | 29.5 ± 6.8 | ||
2 | Lake Zurich water + 10 μM formate | reference for high Rct | 7.4 × 10–9 | 33.8 ± 3.9 | +15 | 1 |
3 | Lake Zurich water + 4 μM NH4+ | NH4+ as HOBr quencher | 4.3 × 10–9 | 18.9 ± 0.8 | –36 | 1 |
4 | Lake Zurich water + 7 μM NH2Cl | NH2Cl as HOBr/Br• quencher | 5.6 × 10–9 | 11.8 ± 1.1 | –60 | 1 |
5 | Lake Zurich water + 15 μM NH2Cl | NH2Cl as HOBr/Br• quencher | 9.9 × 10–9 | 7.9 ± 0.7 | –73 | 1 |
–77 | 2 | |||||
–58 | 3 |