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. 2023 Mar 30;57(47):18710–18721. doi: 10.1021/acs.est.2c09824

Table 1. Second-Order Rate Constants between Biomolecules and Disinfectantsa.

      apparent second-order rate constant (M–1·s–1)
No. compounds PFA (pH = 5.5) PFA (pH = 7.1) PAA (pH = 7.0) PPA (pH = 7.0) free chlorine (pH = 7.0)
amino acids
1 glycine <0.1 <0.1 slow45 <0.1 1.5 × 1053
2 proline <0.1 <0.1 slow45 <0.1 3.5 × 1033
3 glutamic acid <0.1 <0.1 slow45 <0.1  
4 aspartic acid <0.1 <0.1 slow45 <0.1  
5 tyrosine 0.130 <0.1 slow45 <0.1 4.4 × 10174
6 tryptophan 0.225 <0.1 slow45 <0.1 1.1 × 10474
7 serine <0.1 <0.1 slow45 <0.1 1.7 × 1053
8 cysteine >1 × 105 >1 × 105 >1 × 105 >1 × 105 3.0 × 10774
9 methionine >1 × 105 >1 × 105 >1 × 105 >1 × 105 3.8 × 10774
10 lysine <0.1 <0.1 slow45 <0.1 5.0 × 10374
11 arginine <0.1 <0.1 slow45 <0.1 2.6 × 1013
12 histidine 0.294 <0.1 1.862 0.833 1.0 × 10574
ribonucleotides
1 adenosine monophosphate <0.1 <0.1 slow45 <0.1 6.43
2 guanosine monophosphate <0.1 <0.1 slow45 <0.1 2.1 × 1043
3 uridine monophosphate <0.1 <0.1 slow45 <0.1 5.5 × 1033
4 cytidine monophosphate <0.1 0.254 slow45 <0.1 6.6 × 1013
a

Note: The rate constants without notation for references were acquired in this study.