Table 3.
Ni(II)-β-CD as a catalyst in preparing coupling products.
| Entry | Aryl halide | Producta | Time (h) | Yieldb (%) | M.p. (oC)Ref |
|---|---|---|---|---|---|
| 1 | ![]() |
![]() |
5 | 97c | 68–7058 |
| 2 | ![]() |
6 | 95c | 87–8958 | |
| 3 | ![]() |
6 | 94c | 46–4758 | |
| 4 | ![]() |
6.5 | 85 | 70–7258 | |
| 5 | ![]() |
8 | 90 | 110–11258 | |
| 6 | ![]() |
8 | 91 | 84–8658 | |
| 7 | ![]() |
7.5 | 89 | 75–7958 | |
| 8 | ![]() |
![]() |
8 | 90 | 68–7058 |
| 9 | ![]() |
12 | 91 | 84–8658 | |
| 10 | ![]() |
12 | 87 | 110–11258 | |
| 11 | ![]() |
12 | 85 | 46–4758 | |
| 12 | ![]() |
12 | 86 | 87–8958 | |
| 13 | ![]() |
12 | 92 | 58–5956 | |
| 14 | ![]() |
12 | 90 | 119–12056 |
aReaction status: aryl bromide/iodide, K2CO3, phenylboronic acid (with the ratio: 0.5:0.75:0.75), and water (1 mL) under an argon atmosphere.
bIsolated yields.
cYields appointed by GC.















