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. 2023 Dec 2;13:21268. doi: 10.1038/s41598-023-48592-6

Table 2.

Chemical characteristics of clusters of soil samples introduced in the study.

Variable Kruskal–Wallis p value Tree clusters Saline site
Cluster forest 1 Cluster forest 2 Cluster urban 3 Cluster urban 4 Inowrocław-Mątwy45
Salinity
  C-org (%) Ns1 1.7 ± 0.55 2.3 ± 0.76 2.2 ± 0.32 2.1 ± 0.42
 Major nutrients
  N-NH4 (mg/l) Ns 9.2 ± 3.4 6.6 ± 3.1 7.3 ± 1.2 12 ± 2.1
  N-NO3 (mg/l) 0.011 21 ± 15 b 52 ± 14 a 24 ± 5.4 b 21 ± 4.7 b
  P (mg/l) 0.0016 5.0 ± 0.0 c 17 ± 8.3 bc 44 ± 12 a 34 ± 11 ab
  K+ (mg/l) 0.018 44 ± 24 b 46 ± 48 b 81 ± 19 ab 132 ± 39 a 34 ± 1.0
  Na+ (mg/l) 0.0015 23 ± 3.4 b 27 ± 11 b 74 ± 48 ab 439 ± 230 a 280 ± 7.4
  Cl (mg/l) 0.0065 26 ± 4.2 b 28 ± 11 b 38 ± 12 ab 154 ± 81 a 590 ± 12
 Mg2+ (mg/l) 0.00081 24 ± 9.0 b 67 ± 20 ab 136 ± 9.3 a 78 ± 18 ab 14 ± 0.5
 Acidity
  Ca2+ (mg/l) 0.0045 221 ± 96 b 1241 ± 560 ab 1877 ± 269 a 1561 ± 687 a 90 ± 3.5
  pHH2O 0.0032 4.6 ± 0.63 b 6.5 ± 1.0 ab 7.5 ± 0.19 a 7.8 ± 1.0 a
  Fe2+ (mg/l) 0.0056 279 ± 50 a 102 ± 54 ab 56 ± 35 b 95 ± 72 ab
  Mn (mg/l) Ns 36 ± 30 5.1 ± 6.8 4.3 ± 1.9 3.0 ± 1.2
 Heavy metals
  Zn (mg/l) 0.0015 2.9 ± 1.2 b 13 ± 8.2 ab 20 ± 3.9 a 47 ± 21 a
  Cu (mg/l) 0.0012 1.2 ± 0.39 b 1.1 ± 0.35 b 5.5 ± 1.6 a 12 ± 3.4 a
  Pb (mg/kg) 0.013 28 ± 15 ab 20 ± 7.9 b 33 ± 9.1 ab 70 ± 47 a
  Cd (mg/kg) 0.0067 0.15 ± 0.06 b 0.41 ± 0.29 ab 0.34 ± 0.18 ab 0.94 ± 0.57 a
Geo-accumulation index
  Zn (Igeo) Not performed − 4.6 ± 0.61 − 2.5 ± 0.94 − 1.8 ± 0.28 − 0.6 ± 0.64
  Cu (Igeo) Not performed − 4.3 ± 0.46 − 4.5 ± 0.45 − 2.2 ± 0.41 − 1.1 ± 0.42
  Pb (Igeo) Not performed − 0.093 ± 0.79 − 0.56 ± 0.56 0.14 ± 0.4 1.2 ± 0.96
  Cd (Igeo) Not performed − 0.010 ± 0.61 1.5 ± 1.0 1.2 ± 0.79 2.7 ± 0.88

Means and standard deviations of selected chemical properties and pH of soil samples within each cluster of trees. Results of the Kruskal–Wallis test for the differences between the concentrations of each of the chemical components with the homogenous groups of clusters. The geo-accumulation index values85 were computed for the HM in each cluster (the Kruskal–Wallis test was not performed in that case) in comparison to the geochemical background46.

Ns non-significant.