Activation parameters of the dissolution of SS304 in 1.0 M HCl with and without SCPs at 25–45 °C.
Inhibitor | Conc., ×106 M |
![]() |
ΔH*, kJ mol−1 | −ΔS*, J mol−1 K−1 |
---|---|---|---|---|
Blank | 0.0 | 66.4 ± 0.2078 | 63.9 ± 0.2071 | 78.2 ± 0.1341 |
SCP1 | 7 | 78.1 ± 0.1202 | 75.6 ± 0.0882 | 52.7 ± 0.1453 |
10 | 79.8 ± 0.0882 | 77.3 ± 0.1528 | 53.8 ± 0.1202 | |
13 | 81.1 ± 0.2603 | 78.6 ± 0.2028 | 52.9 ± 0.2028 | |
16 | 82.9 ± 0.2887 | 80.4 ± 0.1202 | 59.1 ± 0.1528 | |
SCP2 | 7 | 76.9 ± 0.2309 | 74.4 ± 0.1155 | 53.9 ± 0.2028 |
10 | 78.2 ± 0.1528 | 75.7 ± 0.1764 | 54.6 ± 0.2082 | |
13 | 78.8 ± 0.1856 | 76.3 ± 0.2404 | 42.9 ± 0.1764 | |
16 | 81.1 ± 0.1732 | 78.6 ± 0.1732 | 48.6 ± 0.2404 |