Influence of different catalyst amounts and temperatures on the model studya.
| Entry | Catalyst amount (g) | Temp. (oC) | Time (min) | Yieldb (%) |
|---|---|---|---|---|
| 1 | 0.007 | 80 | 100 | 72 |
| 2 | 0.007 | 90 | 100 | 86 |
| 3 | 0.007 | 100 | 40 | 90 |
| 4 | 0.007 | 110 | 10 | 98 |
| 5 | 0.007 | 120 | 10 | 98 |
| 6 | 0.005 | 110 | 15 | 94 |
| 7 | 0.01 | 110 | 10 | 98 |
Reaction conditions: UiO-66-NH2-MOF@COF, isatoic anhydride (1 mmol), 4-nitrobenzaldehyde (1 mmol), and aniline (1 mmol).
Isolated yield.