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. 2023 Nov 3;14(47):13783–13798. doi: 10.1039/d3sc04186g

Changes in initial parameters for water content and SEI to study the effect of different manufacturing and ageing conditions: reference scenario, organic or inorganic SEI, thick or thin SEI, wet or dry electrode.

Parameter Scenario
Reference Thick SEI Thin SEI Organic SEI Inorganic SEI Wet electrode Dry electrode
d SEI/nm 50 75 25 50 50 50 50
ε LEDC/vol% 45 45 45 90 0 46 45
ε Li2CO3/vol% 34 34 33 8.4 39 30 34
ε LiF/vol% 10.4 10.4 11.4 1 30.4 9 10.6
ε Li2O/vol% 10 10 10 0 30 10 10
ε LiOH/vol% 0.6 0.6 0.6 0.6 0.6 5 0.4
C H2O/ppm 260 260 260 260 260 505 168
C HF/ppm 0 0 0 0 0 0 0
C PF3/ppm 992 992 992 992 992 880 1017
C POF3/ppm 46 46 46 46 46 95 31
C HPO2F2/ppm 1306 1306 1306 1306 1306 5332 536