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. 2023 Dec 8;13(51):35831–35840. doi: 10.1039/d3ra05794a

Thermal properties of polysaccharides before and after UO22+ adsorptiona.

Step G U–G
Onset temp. (°C) DTG (°C) Wt loss (%) Onset temp. (°C) DTG (°C) Wt loss (%)
Step 1 73.55 6.02 79.01 3.85
Step 2 149.61 314.90 80.66 166.75 268.91 37.93
Step 3 318.06 334.20 20.43
404.85
Residue 13.31 37.75
X U–X
Step 1 114.64 4.36 68.85 6.23
Step 2 176.84 275.17 65.68 154.65 273.19 33.55
Step 3 350.34 348.39 11.07
Step 4 600.5 857.25 6.04
Residue 29.94 43.14
I U–I
Step 1 87.44 6.92 71.49 9.67
Step 2 137.24 164.84 25.02 156.67 222.92 18.59
Step 3 184.98 256.15 12.81 300.91 356.73 6.87
Step 4 307.36 351.05 12.11 393.72 443.93 10.29
Step 5 599.95 747.71 16.61 509.72 601.06 13.26
Residue 26.54 37.05
K U–K
Step 1 69.19 9.31 76.24 7.07
Step 2 146.58 259.39 22.39 156.67 278.44 28.40
Step 3 277.71 321.94 23.10 395.73 440.94 22.82
Step 4 500.64 747.92 17.04
Residue 28.16 41.72
a

Sorption conditions: 700 mg per L UO22+, 3 mL of 1% w/v polysaccharide.