Table 2.
FT-IR bands of NLP absorption corresponding to chemical bonds.
| Sl. No | Absorption Potential (cm−1) |
Functional groups | Band strength | Probable peak range (cm−1) | Related chemical fractions | References |
|---|---|---|---|---|---|---|
| 1 | 3338.46 | O–H O–H -N-H >N–H |
Strong, broad | 3200–3570 3200–3400 3325–3345 3310–3360 |
Alcohol Polymeric compound Aliphatic primary amine Aliphatic secondary amine |
[59] |
| 2 | 2916.32 | C–H, >CH2 | Weak, sharper | 2915–2935 | Saturated aliphatic alkene (Methylene) | [60] |
| 3 | 2848.49 | C–H, >CH2 | Weak, sharper | 2845–2865 | Saturated aliphatic alkene (Methylene) | [61] |
| 4 | 1629.16 | C
C R2C O, –C(=O)–N O -C N–N N-R-N N–R |
Medium, sharp | 1600–1700 1620–1680 1620–1640 1600–1650 1590–1690 1575–1630 |
Alkenes Olefinic alkenes (Alkenyl group) Organic nitrates Conjugated ketone (Quinone) Open-chain imino group Open-chain azo group |
[62,63] |
| 5 | 1420.88 | v-C-H R–COOH or R–CO₂H |
Weak, in plane stretch | 1410–1420 1300–1420 1200–1600 |
Olefinic alkenes Carboxylic acid salt (Carboxylate) Carboxylic acid, Saturated aliphatic ester |
[64,65] |
| 6 | 1317.49 | C–N C–OH/Ph-OH P O R–SO2-O-R, S O |
Weak | 1250–1360 1310–1410 1250–1350 1300–1335 |
Aromatic primary/secondary/tertiary amines Phenol or tertiary alcohol bend Organic phosphates Dialkyl/aryl sulfonates (esters) |
[66] |
| 7 | 1247.72 | Aryl-O-CH2 Aryl-O-CH3 |
Weak | 1230–1270 ∼1250 |
Aromatic ethers Aromatic ethers (Epoxy/oxirane ring) |
[67,68] |
| 8 | 1158.34 | C–N C–N R–S(=O), S O |
Weak, in plane stretch | 1130–1190 1150–1210 1100–1200 |
Aliphatic secondary amine Aliphatic tertiary amine Sulfonates |
[69,70] |
| 9 | 1101.68 | C–H C–F |
Weak | 950–1225 1000–1150 |
Aromatic ring (aryl group) Aliphatic fluoro compound (halogenated) |
[71,72] |
| 10 | 1028.27 | >CH2 P–O–C N–C–H Si–O–Si |
Strong, sharp | 925–1055 990–1050 1020–1090 1020–1055 |
Methylene, cyclohexane ring Aliphatic phosphates Primary amine Organic siloxane |
[73,74] |
| 11 | 898.99 | vinyl-C-H, C
CH2 C–H |
Weak, out of plane stretch | 890–915 800–900 600–1000 |
Olefinic alkene Aromatic 1,3 para/meta distribution Alkyl halides, glycosides |
[75,76] |
| 12 | 812.81 | C–H | Weak | 800–900 800–890 |
Aromatic 1,3 para/meta distribution Aromatic ethers (Epoxy/oxirane ring) |
[77,78] |
| 13 | 715.45 | C–Cl R–S–C(=O)−R |
Weak, out of plane stretch | 700–800 670–715 |
Aliphatic chloro compound (halogenated) Aryl thio-esters (C-5) |
[79,80] |
| 14 | 582.99 | C–S/R–S–S−R′ | Weak stretch | 570–705 | Disulfides | [81,82] |